Thermal insulation materials reduce heat transfer between two environments at different temperatures. There are concepts such as thermal conductivity, heat permeability resistance, and heat transmission coefficient in thermal insulation.
For example, when the temperature difference between two parallel surfaces of a homogeneous material with a thickness of 1 m is 1°C and this temperature remains constant, the amount of heat energy passed per unit time is called thermal conductivity (λ,W/mK) (Aydin 2010). The thermal conductivity resistance is the total value of how much heat is transmitted and depends on the thickness of the material (Çöl 2020). When the temperature difference between the two sides of a building element with 'd' thickness is 1°C under constant conditions, the amount of heat energy passing through the unit area per unit time is defined as the heat transmission coefficient and is denoted by 'u'; its unit is W/m²K (Aydın 2010). The most basic feature of thermal insulation materials is the heat transmission coefficient.
According to the International Standards Organization (ISO) and the European Standardization Committee (CEN), materials with a heat transmission coefficient less than 0.065 W/mK are defined as thermal insulation materials. Other materials are defined as building materials (TS 825).
The desired properties of thermal insulation materials include low thermal conductivity, low unit volume mass, fire resistance, vapor diffusion resistance, water absorption, sufficient compressive strength, resistance to chemical effects, incorruptibility, being parasite-free, economical, and processable (Ozer and Ozgunler 2019).
Traditionally, people used natural materials such as animal skins, fur, wool that were used for clothing in the nomadic living conditions of 7000 BC and before as thermal insulation materials in buildings. From the 1870s AD onwards, they built their houses using more durable materials such as soil, wood, bricks, and also used plant fibers such as straw, seaweed, and reeds. At the end of the 19th century, with the excessive increase in energy consumption as a result of the industrial revolution, and energy-saving awareness and heat loss calculations started in this period. Following these developments, industrial production of thermal insulation materials began. The use of plastics became widespread between 1950 and 2000, and after 2000, as a result of the environmental effects caused by plastic material production, a tendency to return to natural materials has arisen. With the developing technology, new materials such as aerogels and vacuum insulation panels have been produced (Bozasky 2010).
In this study, thermal insulation materials were divided into three groups to examine. Rock wool, glass wool, EPS, and XPS as commonly used thermal insulation materials were examined and aerogels which are thermal insulation materials with nanotechnology and vacuum insulation panels were discussed. The materials of vegetable and animal origin were limited to goat hair, wool, flax, straw, and hemp as alternative thermal insulation materials used in history within the scope of this study.
Rock wool is produced by turning stones such as dolomite, basalt, and diabase into the fiber at 1400-1600°C. By using binders such as starch, oil, and resins, they can be bonded together to obtain fiber. The fiber can be processed in the form of panels, rolls, mattresses, felts, pipes, and casts in different sizes and thicknesses depending on the place and purpose of use. It is widely used to provide fire safety behind the cladding and on ventilated facades, as it is resistant to heat and humidity, and generally non-flammable (Kirbiyik 2012). Rock wool and glass wool are similar in terms of their ecological properties, and rock wool can be recycled by manufacturers or disposed of in landfills (Woolley 2005).
Glass wool: a thermal insulation material produced at 1300-1450°C by mixing natural silica sand and usually recycled glass. Glass wool fibers are bonded by adding dust-preventing oil and phenolic resins (Arslan and Aktaş 2018). It is produced in different sizes and densities, in the form of plates, pipes, mattresses, and casts, depending on the place and purpose of use (Kirbiyik, 2012). It may change in size under external force. Energy usage is high as raw materials are melted at high temperatures. It may cause skin, larynx, and chest diseases due to dust and particles during production. It is potentially harmful to local soil quality due to limestone and silica extraction for raw material. As glass wool is thought to have a negative impact on air quality, it serves areas such as ground filling when recycled (Arslan and Aktas 2018).
EPS(expanded polystyrene foam): A petroleum-based, thermoplastic, closed-pore thermal insulation material in the form of foam. It is produced by inflating and fusing polystyrene particles by using pentane. 98% of EPS is still air. It can be processed in the form of blocks and cuttable sheets, depending on the place and purpose of use (Bayer 2006). Although it is chemically resistant to solvents, it may be affected by sunlight. It does not decay. Ecologically, there is a high energy use due to the use of petrochemicals, oil, and gas as raw materials. In addition, wastes such as heavy metals may occur during production. It may create a toxic effect by releasing carbon monoxide and carbon dioxide smoke and vapor in case of fire. EPS can be recycled by specialized organizations (Arslan and Aktas 2018).
XPS (extruded polystyrene foam): A thermal insulation material produced by extrusion machine by adding expansion gases and fire retardant to melted polystyrene. It can be sized and cut according to the place and purpose of use. It has low water absorption due to its closed porous structure. In this context, it is mostly used on pitched roofs and insulation of sandwich walls. It is also preferred in underground insulations and floors where high compressive strength is desired (Ozer and Ozgunler, 2019). Ecologically, although it has similar characteristics with EPS, it can be harmful to the environment due to the use of hydrofluorocarbon (HFC) and carbon dioxide (CO2) gas instead of pentane (Arslan and Aktas 2018).
Aerogels: It is a material discovered in the 1930s and primarily used in space applications. Since the 1980s, it has been a material of interest for use in building applications due to its high insulating properties and transparency (Buratti et al., 2021). Aerogels are the lightest additives in the literature. They are produced by combining a polymer with a solvent to form a gel, and then removing the liquid from the gel and replacing it with air. Aerogel contains nano-sized voids and has a porous structure in the range of 90-98%. Hence, it has a low unit volume mass. It can be produced from different materials such as silica, organic polymers, metal oxides, carbon, and metals (Yilmaz 2013). Although it is resistant to a temperature of approximately 1200°C, discoloration does not occur due to the long-term effect of sunlight. It is also resistant to moisture and mold formation. Aerogels are resistant and do not lose their properties in the long term (Ozer and Ozgunler 2019). The thermal insulation performance and optical transparency of airgels allow their use in windowpanes and solar collector covers. Due to their low thermal conductivity and acoustic properties for noise reduction, aerogels can be used in buildings, as well as for indoor air quality, for photocatalysis in environmental cleaning, and in fire retardant sheets with non-flammability. (Riffat and Qiu 2013).
Vacuum insulation panels: Vacuum insulation panels (VIPs) are recognized as one of the high-performance thermal insulation solutions. They are made by utilizing the vacuum environment where heat conduction is low. The air in the insulation product is removed by vacuuming with nanotechnology. In this way, much thinner and low thermal conductivity panels are obtained (Baetens et al., 2010). These panels are usually produced by vacuuming different porous filling materials placed between aluminum-containing film, plastic, or stainless steel-covered protective barriers (Kumlutas and Yilmaz, 2008). Although they have a long service life, they may lose their thermal insulation properties when punctured. As custom products, they are also difficult to process. Since they are largely impermeable, condensation problems may occur (Arslan and Aktas 2018).
Goat hair: A natural material that has been used in Turkish culture throughout history. In the literature review, no specific heat insulation material produced with goat hair was found. However, cover materials made of goat hair and used in local tents are mentioned to have high thermal insulation performance in many sources.
Goat hair is environmentally friendly as it is a renewable natural raw material. They can be easily transported and used in building without any health hazards. It does not require any protective clothing, masks, or goggles for installation in the building. It has good thermal properties thanks to the proteins called keratin in its physical and chemical structure. It exhibits low thermal conductivity with its natural properties (Ahmed et al. 2019).
Wool: It has been used in clothing since ancient times, as it exhibits good thermal insulation performance. It shows a good acoustic performance thanks to its natural structure. Acoustic performance values increase depending on the thickness and density of wool fibers (Berardi and Iannace, 2015).
Flax: Flax fibers are produced from a plant that has been used since 5000 BC by the Egyptians. The flax contains about 70% cellulose. Flax fibers retain air and have high insulation properties. The elasticity of the fibers also allows them to be used as impact and sound insulators. Flax fibers are often mixed with polyester to increase mechanical resistance, and with additives such as boron salts to increase fire and moth resistance. Flax and hemp can be mixed to produce high-performance thermal insulation material. Flax is easy to grow in any soil without the need for fertilization or purification. When polyester fiber is not used in flax, its waste can be reused, recycled, and used for fertilizer production (Arslan and Aktas 2018).
Hemp: It is not subject to a standard as a heat insulation material.
Hemp fiber is produced from hemp and post-harvest parts of the plant. Hemp, as an insulation material, has a high tendency to retain moisture. As the moisture content increases, the heat transfer coefficient of the material increases. It must be protected from moisture, rodents, and insects. Due to its low compressive strength, it can be used between the wooden frame system, on the lower surfaces of the roof, walls, and for slabs, where it will not be under load (Ozer 2017). The fire risks of cellulose-containing materials such as hemp can be resolved when treated with fire retardant chemicals (Oldham et al., 2011).
Straw: It is known to be used in mud bricks dating to 8300 BC and in ancient Egyptian tombs. In Turkey, straw is a material that can be renewed annually and is abundant and easy to find at certain times. In areas where grain production is available, the stalks of crops such as wheat, oats, rice, and barley are considered waste and discarded, mostly by burning. However, shelters with high energy performance can be built with this material. Strawbale containing cellulose has good insulating properties. Grain-free straw is available every year and is a renewable resource. In a sustainable system, straw can be regrown in less than a year (Irkli Eryildiz and Baskaya 2000).
The properties of the thermal insulation materials examined within the scope of the study with literature review are summarized in Table 1. Considering the thermal conductivity values, aerogels show the lowest performance after vacuum insulation panels. The thermal conductivity values of commonly used thermal insulation materials are very close to each other. Thermal conductivity values of alternative thermal insulation materials are also very close to each other. Unit volume mass values differ in all materials. All groups except alternative thermal insulation materials have resistance to parasites and incorruptibility properties. Processability is possible almost in all materials, except it is difficult in vacuum insulation panels. Also, vacuum insulation panels have the highest vapor diffusion resistance. In literature, there is a lack of data in alternative thermal insulation materials compared to other materials.
Table 1
Thermal Insulation Material Properties Summary Table (TS 825) (Ozer 2017) (Arslan and Aktas 2018) (Ahmed et. al. 2019)
| COMMONLY USED THERMAL INSULATION MATERIALS | THERMAL INSULATION MATERIALS WITH NANOTECHNOLOGY | ALTERNATIVE THERMAL INSULATION MATERIALS |
MATERIAL PROPERTIES | GLASS WOOL | ROCK WOOL | EPS | XPS | AEROGEL | VAC. INSULATION PANEL | GOAT HAIR | WOOL | FLAX | STRAW | HEMP |
Thermal conductivity (W /m. oC) | 0.035- 0.050 | 0.035- 0.050 | 0.035- 0.040 | 0.030- 0.040 | 0.013 - 0.024 * | ≤0.0053 | 0.036-0.073** | 0.038-0.054 | 0.038-0.075 | 0.058 | 0.040- 0.050 |
Unit volume mass (kg/m3) | 15- 150 | 20- 200 | ≥15 | ≥25 | 70- 150 * | 210 | 214-269** | 10-25* | 20 -100* | 150 | 20- 68 |
Avg. Water Absorption | High | High | Low | Low | High | Low | | | High | High | High |
Vapor diffusion resistance (µ) | 1 | 1 | 20- 100 | 80- 250 | 5 | ∞ | | | 2,9* | 3 | 1 2 |
Compressive strength (kPa) | 15-80 | 15-80 | 60- 200 | 150- 700 | >80 | ≥150 | | | | | |
Resistance to parasites | Good | Good | Good | Good | Good | Good | Bad | Bad | Bad | Bad | Bad |
Indefectibility | Does not decay | Does not decay | Does not decay | Does not decay | Does not decay | Does not decay | May decay | May decay | May decay | May decay | May decay |
Processability | easy | easy | easy | easy | easy | difficult | easy | easy | easy | easy | easy |
(—): No data found |
(* Arslan and Aktas, 2018) (**Ahmed et.al, 2019) |