Sites set aside for the dumping of municipal solid waste (MSW) are not used for any other purposes other than the dumping of refuse. Aside from the stench released from the dumpsites, which pollutes the air, the major issue is the dispersion of leachate from the MSW sites into the groundwater aquifers within the dumpsites and the contiguous groundwater resources. This research aims at using an integrated technique to valorize the effect of leachate from MSW sites in Uyo and Eket on the groundwater resources. Geo-electrical technology involving vertical electrical techniques and constant electrode separations were used to acquire 1D and 2D resistivity data. The interpreted resistivity results constrained by ground-truthing data were combined with hydro-physiochemical analysis to valorize the effect of MSW sites on groundwater. The VES curve types in the survey area are primarily K (57.1%), HK (21.3%), Q (14.3%) and H (7.3%), which exhibit the intercalations of various lithological suites. The inferred image maps at MSW sites showed a dispersion of leachate, which appears to follow the inverse square law between the source and the sink. The BOD-COD ratio revealed that the waste is partially biodegradable. The analyses of hydro-geochemistry of surface and groundwater in the area showed a sequence of average abundance of cations of light metals in the order:; heavy metals as:. The anionic average relative abundance takes the following order:. The use of surface water and groundwater resources for irrigation in the MSW sites has been found to be dependent on the sodium adsorption ratio and total hardness required by the crops. With the results of this study, the valorization of the ingress of leachate into groundwater resources near the MSW sites should be assessed annually to ameliorate the unfortunate environmental hazards.