13C NMR of PAMS
In order to comprehend the architecture of polymer chains, it is imperative to gain insight into the correlation between their structure and characteristics [17]. Primarily, owing to its superior resolution and broader spectral range, 13C NMR spectroscopy is employed for determining the tacticity of polymers [18]. In 13C NMR spectra, each peak can be associated with a distinct sequence characterized by a unique chemical shift. Figure 1 illustrates 13C NMR of PAMS II with narrow Đ (obtained by GPC, Fig. 2) and with the chemical shifts correspond to various carbon types, including α-methyl carbon, methylene carbon, quaternary aliphatic carbon, quaternary aromatic C1 carbon, and C2, C3, and C4 carbons. These carbon atoms exist within diverse isomeric environments along the polymer chain, leading to mutual influences among neighboring carbon atoms. In this study, the investigation of stereospecificity focused on methylene, quaternary aliphatic, and quaternary aromatic carbons. These assignments are adapted to our previous research [27].
The 13CNMR spectra of quaternary aromatic carbon are depicted in Fig. 3a. The quaternary aromatic carbon within the molecular chain of PAMS exhibits symmetry with varying stereospecificity. Figure 3a illustrates the splitting of the quaternary aromatic carbon into 8 pentad sequences. Hence, in statistical analysis, pentad sequence distributions reveal that the left section is abundant in meso sequences, while the right section is enriched with racemic ones. The upfield region of the quaternary aliphatic carbon of PAMS is enriched with isotactic sequences, whereas the downfield region is abundant in syndiotactic sequences. [19]. The distribution of sequences, assignment of chemical shift, experimental peak intensity, and intensities calculated from Bernoullian and 1st-order Markov statistics for the pentad sequences are presented in Tables 2. Notably, the measured and calculated values, in accordance with Bernoullian statistics, demonstrate satisfactory agreement. Within the domain of statistical analysis, meso (Pm) and racemic (Pr) sequence probabilities are defined by equations (11) and (12) respectively. The rr, mr, and mm triad sequences denote the syndiotactic, atactic, and isotactic segments of the chain respectively [20].
Pm = (2mm + mr)/2 (1)
Pr = (2rr + mr)/2 (2)
The relationship among pentad, triad, and dyad structures (as defined in equations 3–5) facilitate the deduction of meso sequence probabilities from higher sequences [19].
mm = mmmm + mmmr + rmmr (3)
mr = mmrm + mmrr + rmrm + rmrr (4)
rr = mrrm + mrrr + rrrr (5)
Table 2
Normalized pentad sequences of quaternary aromatic carbon, calculated Bernoullian and 1st -order Markov statistics for PAMS synthesized via living anionic polymerization
Peak No.
|
Pentad Microstructure
|
Chemical shift
|
Obs.
|
Cal.a
|
Cal.b
|
1
|
mrrm
|
152.69
|
0.0286
|
0.0375
|
0.0215
|
2
|
mrrr + rrrr
|
152.12
|
0.2030
|
0.4997
|
0.5546
|
3
|
rmrr
|
151.38
|
0.4036
|
0.2071
|
0.1323
|
4
|
mmrm
|
150.75
|
0.0257
|
0.0285
|
0.1232
|
5
|
rmrm
|
150.58
|
0.1474
|
0.0814
|
0.0584
|
6
|
mmrr
|
150.35
|
0.0448
|
0.0795
|
0.0670
|
7
|
rmmr
|
150.17
|
0.0389
|
0.0393
|
0.0220
|
8
|
mmmr + mmmm
|
150.06
|
0.0892
|
0.0270
|
0.0210
|
a) Bernoullian statistic equation, Average sum square difference: 1.12×10− 1 |
b) 1st -order Markov statistic equation, Average sum square difference: 2.09×10− 1 |
By integrating the areas of sequences depicted in Fig. 3 and applying equations 1–5, the calculated value of Pm for all samples is determined to be 0.439. This suggests that the synthesis of PAMS samples exhibits some deviation from the ideal random case (Pm=0.5), with the degree of racemic addition consistently surpassing that of meso addition. This trend may be attributed to the stereohindrance of pendant groups, which tend to spatially segregate and form racemic sequences. Comparing this result with our findings in the previous work, Pm value of synthesized PAMS via living anionic polymerization is much closer to ideal random case rather than those synthesized via photopolymerization at two different temperatures [19]. However, all polymerization condition suggests Pm<0.5, which represents racemic addition predominates over meso addition in PAMS synthesis.
In line with Bernoullian and 1st -order Markov statistical models, the formation of polymeric chains can be anticipated. For instance, in the 1st -order Markov model, the configuration of the new monomer is influenced by the preceding sequence to which it is added. By evaluating the sum of squared differences between the two models and experimental data, adjustments to the Bernoullian and 1st -order Markov models can be made for all carbon atoms. Table 2 reveals that for all carbons, the Bernoullian statistics model more effectively predicts the formation of monomers in polymer propagation.
Expanded 13CNMR of quaternary aliphatic carbon
The 13CNMR spectrum of quaternary aliphatic carbon is depicted in Fig. 3b. The quaternary aliphatic carbon within PAMS exhibits asymmetry, rendering it prone to monomer insertion along the molecular chains. Additionally, the resonance of this carbon displays unique chemical shifts attributable to the microstructure of PAMS. As depicted in Fig. 3b, the quaternary aliphatic carbon undergoes a splitting into 10 pentad sequences. The upfield portion of the spectrum exhibits an abundance of isotactic sequences, whereas the downfield region predominantly features syndiotactic sequences. The normalized data are presented in Table 3. The comparison between these two statistical models also involved assessing the sum of squared differences between observed and calculated data. These comparative data are additionally presented in Tables 3.
Table 3
Normalized pentad sequences of quaternary aliphatic carbon, calculated Bernoullian and 1st -order Markov statistics for PAMS synthesized via living anionic polymerization
Peak No.
|
Pentad Microstructure
|
Chemical shift
|
Obs.
|
Cal.a
|
Cal.b
|
1
|
mrrm
|
44.75
|
0.0261
|
0.0369
|
0.0156
|
2
|
mrrr
|
44.48
|
0.0979
|
0.1611
|
0.1326
|
3
|
rrrr
|
44.39
|
0.2341
|
0.2450
|
0.5977
|
4
|
rmrr + mmrm
|
43.76
|
0.1366
|
0.2526
|
0.0665
|
5
|
mmrr + rmrm
|
43.59
|
0.1989
|
0.1435
|
0.0932
|
6
|
rrmmrr
|
43.46
|
0.0273
|
0.0203
|
0.0152
|
7
|
mrmmrr + mrmmrm
|
43.37
|
0.0352
|
0.0278
|
0.0045
|
8
|
rmmmrr
|
43.13
|
0.0456
|
0.0223
|
0.0175
|
9
|
mmmmrr + rmmmrm + mmmmrm
|
42.72
|
0.0972
|
0.0076
|
0.0336
|
10
|
mmmmmm + mmmmmr + rmmmmr
|
42.61
|
0.1011
|
0.0829
|
0.0236
|
a) Bernoullian statistic equation, Average sum square difference: 2.97×10− 2 |
b) 1st -order Markov statistic equation, Average sum square difference: 1.61×10− 1 |
Expanded 13CNMR of methylene carbon
In Fig. 3c, the 13C NMR spectrum of the methylene carbon, a symmetric carbon, is illustrated. The spectrum reveals a splitting of the methylene carbon into 16 hexad sequences. Table 4 presents the normalized data for these hexad sequences, accompanied by the sum of squared differences between observed and calculated data. Notably, the measured data demonstrates a close agreement with the calculated values derived from Bernoullian statistics.
Table 4
Normalized hexad sequences of the methylene carbon, calculated Bernoullian and 1st -order Markov statistics for PAMS synthesized via living anionic polymerization
Peak No.
|
Hexad Microstructure
|
Chemical shift
|
Obs.
|
Cal.a
|
Cal.b
|
1
|
mrmrm
|
61.75
|
0.0423
|
0.0109
|
0.0265
|
2
|
rrmrm
|
61.49
|
0.0523
|
0.0511
|
0.0098
|
3
|
rrmrr
|
61.35
|
0.0520
|
0.0912
|
0.0107
|
4
|
mmmrr
|
61.07
|
0.0205
|
0.0201
|
0.0752
|
5
|
mmmrm
|
60.62
|
0.0236
|
0.0132
|
0.0119
|
6
|
rmmrr
|
60.57
|
0.0368
|
0.0256
|
0.0398
|
7
|
rmmrm
|
60.39
|
0.1398
|
0.0432
|
0.0615
|
8
|
rrrm
|
60.24
|
0.1251
|
0.0985
|
0.0632
|
9
|
rrrrr
|
60.07
|
0.0836
|
0.2379
|
0.3798
|
10
|
mrrrm
|
59.92
|
0.1386
|
0.0675
|
0.0108
|
11
|
mmm
|
59.83
|
0.0417
|
0.0295
|
0.0161
|
12
|
mrm
|
59.02
|
0.0123
|
0.0392
|
0.0515
|
13
|
rmrrm
|
58.29
|
0.0553
|
0.0592
|
0.0905
|
14
|
rmrrr
|
58.18
|
0.1239
|
0.1426
|
0.077
|
15
|
mmrrr
|
57.91
|
0.0371
|
0.0505
|
0.0624
|
16
|
mmrrm
|
57.61
|
0.0153
|
0.0198
|
0.0133
|
a) Bernoullian statistic equation, Average sum square difference: 4.30×10− 2 |
b) 1st -order Markov statistic equation, Average sum square difference: 1.27×10− 1 |
1H NMR of PAMS
The 1H NMR spectrum of the synthesized PAMS I is illustrated in Fig. 4. As it can be seen, the peak appeared within the 0.6–1.1 ppm range corresponds to the protons of methyl groups, designated as "a". Similarly, the peak within the 6.4–7.7 ppm range corresponds to aromatic protons, designated as "c". Peaks labeled as "b" are ascribed to the protons of aliphatic methine and methylene groups. Notably, the absence of three peaks characteristic of a doublet of doublet within the chemical range of 4–6 ppm confirms the absence of unreacted monomer within the system [16, 21].
Utilizing 1H NMR as a quantitative methodology offers a straightforward and inherently precise means for determining polymer molecular weights without the need for calibration procedures [22]. Mn of synthesized PAMS I is calculated by assessing the relative intensity of peak of aromatic proton to that of methyl and methylene of repeating unite group [16]. The calculation yields an estimated Mn of 640 gr/mol for the synthesized PAMS I, which closely aligns with the results obtained from GPC analysis. Nonetheless, a minor variance between the results obtained from 1H NMR and GPC analyses arose from the overlap between CDCl3 and aromatic proton peaks. It is imperative to emphasize that the accuracy of Mn determination using 1H NMR spectroscopy is primarily reliable for low molecular weight polymers. This limitation stems from challenges in accurately integrating high molecular weight polymers and the incapacity to detect end groups [16].
Kinetics study
The presence of impurities in living polymerization can considerably impact the end product and properties of the synthesized polymers. Even trace amounts of impurities can disrupt the controlled nature of the polymerization reaction, leading to undesired chain termination or side reactions. This can result in variations in molecular weight, dispersity, and structural defects within the polymer chains. Therefore, meticulous reagent purification assumes paramount importance, given the pivotal role of initiator deactivation contingent upon the absence of impurities such as moisture and oxygen within the system [23, 24]. The impact of these impurities on both molecular weight and the polymerization rate finds elucidation through the scrutiny of GPC distribution plots. Our previous investigation demonstrated the efficiency of utilizing multi-stage initiator dosing for both quantifying the degree of impurity and determining the propagation rate constant (kp) [16]. Cyclohexane serves as an optimal solvent due to its ability to form stable ion pairs between the active sites and counter ions, thereby enhancing the stability of the anionic system [25]. This methodologically sophisticated approach not only enhances our comprehension of initiator purity implications but also underscores the pivotal role of solvent selection in the intricate dynamics of anionic polymerization, offering valuable insights for advanced polymer engineering in high-impact applications.
Figure 5 illustrates the GPC pattern of PAMS III employing a two-stage dosing strategy. The inset graph highlights the correlation between polymer conversion and the polymerization time. Remarkably, both peaks exhibit polydispersity index (Đ) closely aligned with their true values, indicative of a well-controlled polymerization process. As shown in Fig. 5, the peak appeared at higher molecular weight, assigned as “G1”, exhibits a lower intensity compared to peak G2. Furthermore, the recorded conversion rate for step I of dosing was approximately 40%. It is noteworthy that the dissociation of the anionic polymerization initiator before the initiation of the polymerization facilitates the application of simplified classic kinetics for estimation of kp. Consequently, first-order rate equation was used [26]:
$$[M]={[M]_0}{e^{ - {k_p}{{[I]}_0}t}}$$
6
where [M], [M]0 and [I]0 represent the concentration of monomer at time t, the initial concentration of the monomer, and the total concentration of the initiator before dissociation, respectively. [I]0 is the sum of the initial concentration of the pure initiator, [I]0p, which could participate in the polymerization reaction, and the primary initiator concentration, \({\left[ I \right]_{0i}}\), which reacts with impurities. In order to estimate the [I]0p the degree of polymerization should be defined, which can be obtained from the intensity of each peak in GPC graph. Equations 7 and 8 represent the degree of polymerization for each stage [16].
$${X_{n1}}=\frac{{{{\left[ M \right]}_0} - {{\left[ M \right]}_1}}}{{{{\left[ I \right]}_{0p}}}}+\frac{{{{\left[ M \right]}_1} - {{\left[ M \right]}_2}}}{{{{\left[ I \right]}_{0p}}+{{\left[ I \right]}_1}}}$$
7
$${X_{n2}}=\frac{{{{\left[ M \right]}_1} - {{\left[ M \right]}_2}}}{{{{\left[ I \right]}_{0p}}+{{\left[ I \right]}_1}}}=\frac{{{{\left[ M \right]}_1}}}{{{{\left[ I \right]}_{0p}}+{{\left[ I \right]}_1}}}$$
8
where \({\left[ M \right]_1}\) and \({\left[ M \right]_2}\) represent the residual monomer concentration respectively before the 2nd stage of dosing and at the end of polymerization reaction. Xn1 and Xn2 designate the number-average degree of polymerization for peaks G1 and G2, respectively. Moreover, \({\left[ I \right]_1}\) is initiator concentration in the 2nd stage of dosing. The terms on the right-hand side of the equations illustrates degree of polymerization for each stage of dosing. Although, gravimetry analysis endorsed the complete monomer conversion, we proceeded to apply another initiator dosing after given time for other samples under similar experimental conditions. The absence of third peak on GPC spectrum corroborated a 100% monomer conversion for this polymerization method. \({\left[ I \right]_{0p}}\) could be determined by simultaneously solving equations 7 and 8 and using Xn1 and Xn2 values from GPC distribution plot. The obtained parameters were then substituted in the Eq. 1 to attain kp (0.51 L.mol− 1.sec− 1).
It is worth noting to mention that by increasing dosing stage, the accuracy of calculated kp would enhance. Thereupon, PAMS IV synthesized using three-stage dosing of initiator and the corresponding GPC graph is depicted in Fig. 6. The same trend was observed for PAMS IV. Indeed, the peak G1, appeared at higher molecular weight, represents a lower intensity than peaks G2 and G3. This phenomenon suggests the reaction of impurities with initiator at the initial stage of the polymerization [16]. The monomer conversion for this stage was 27%. In order to determine \({\left[ I \right]_{0p}}\)and kp of PAMS IV, three following equations are defined to represent the degree of polymerization for each stage of polymerization:
![](data:image/png;base64,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)
where \({\left[ M \right]_2}\) and \({\left[ M \right]_3}\) represent the residual monomer concentration respectively before the 3rd stage of dosing and at the end of polymerization reaction. Xn1, Xn2 and Xn3 designate the number-average degree of polymerization for peaks G1, G2 and G3, respectively. Moreover, \({[I]_2}\) is initiator concentration in the 3rd stage of dosing. kp value obtained using three-stage dosing of initiator was 0.49 L.mol− 1.sec− 1, showing well agreement among kp obtained by two-stage and three-stage dosing. As a matter of fact, the presence of electron donating methyl group in poly(α-methyl styrene) offers lower reaction rate rather than polystyrene synthesized under the same conditions.
Thermal behavior
The physical characteristics of PAMS are significantly influenced by its molecular weight. Figure 7 illustrates the influence of molecular weight on the thermal stability of the synthesized samples. The initial degradation of PAMS I with a molecular weight of 640 g/mol commenced at around 120°C, while the sample with a higher molecular weight of 3800 g/mol (PAMS II) initiated degradation at approximately 360°C. A wide and distinct multi-stage degradation pattern is evident in the lower molecular weight resin, indicating a more pronounced influence of the repeating unit [16]. 25% weight loss for each stage suggests depolymerization of the repeating unit in this particular sample. Increasing molecular weight restricts polymer mobility and raises the degradation temperature, implying enhanced thermal stability [27]. The effect of molecular weight on glass transition temperature (Tg) is pronounced for the polymers with low molecular weight. As it can be seen from Fig. 7 (inset), a noticeable shift towards higher values of Tg is noted as the molecular weight of PAMS increases. This underscores the correlation between molecular weight and Tg, emphasizing the role of polymerization degree in influencing the glass transition temperature.