Valves Detection is a basic function of rescue robots in various disaster situations. However, due to the small differences between similar valves, rescue robots suffer great challenges in valve detection in complex environments. To address this challenge, this paper proposes a multi-path hybrid attention deep neural network (MHADNN). By weighting features at different scales and spatial positions, the MHADNN can help valve detection models focus on more discriminative subtle features, thereby enhancing the ability to distinguish similar valves. This paper combines the MHADNN with the YOLOv5n to develop a valve detection model. The comparative experiments are conducted on a similar valve dataset collected in the simulated environment of a chemical industrial park. The experimental results show that compared with YOLOv5n, the proposed valve detection model has an average precision improvement of 4.20%. It has excellent performance in distinguishing similar valves.