4.1. Testing material
In this study, the three high-strength fine-grained structural steels S700MC, S960QL and S1100 are analyzed. These steels are chosen to examine not only their strength characteristics but also their different delivery conditions and associated heat treatments. To produce standardized notched impact test specimens measuring 10x10 mm², these steels are utilized at a thickness of 12 mm.
The S700MC is a hot-rolled steel according to DINE EN 10149-2 [29] with a ferritic structure. Micro-alloy elements such as Mn, Ni, or Mo contribute to its excellent formability. On the other hand, S960QL is a quenched and tempered steel with a fine grain structure. Despite having similar delivery conditions to S960QL, S1100 cannot be designated as QL under DIN EN 10025-6 [30] as this standard only covers strengths up to 960 MPa. Both quenched and tempered steels, S960QL and S1100, exhibit a lamellar bainitic-martensitic microstructure. The low Carbon Equivalent Value (CEV) of S700MC enhances its weldability without requiring pre-heating. In contrast, S960QL and S1100 necessitate pre-heating before welding to prevent issues like hardening and cold cracking. The chemical composition was determined using optical emission spectrometry and is shown in Table 1.
Table 1
Chemicals composition of the test materials
| C [%] | Mn [%] | Si [%] | Al [%] | Nb [%] | V [%] | Ti [%] | Mo [%] | Cr [%] | Cu [%] | Ni [%] | CEV [%] |
S700MC | 0,066 | 1,86 | 0,023 | 0,054 | 0,049 | 0,005 | 0,132 | 0,022 | 0,03 | 0,013 | 0,03 | 0,391 |
S960QL | 0,163 | 1,10 | 0,256 | 0,093 | 0,028 | 0,001 | 0,003 | 0,591 | 0,614 | 0,017 | 0,034 | 0,591 |
S1100 | 0,158 | 0,855 | 0,219 | 0,051 | 0,018 | 0,02 | 0,002 | 0,375 | 0,484 | 0,012 | 1,27 | 0,562 |
The mechanical characteristics investigated through tensile tests, as shown in Table 2, provide an initial indication of the formability of the steels. It is evident from the data that the elongation decreases significantly with increasing strength.
Table 2
Material properties of the test material
| yield strength [MPa] | tensile strength [MPa] | elongation without necking [%] | elongation at break [%] |
S700MC | 788 | 840 | 9,3 | 17,6 |
S960QL | 1009 | 1049 | 5,5 | 12,8 |
S1100 | 1189 | 1398 | 3,5 | 10,3 |
4.2. Cold forming
In this article, two cold forming processes, bending and elongation, were investigated. The elongation process involved stretching the material using a tensile machine with a maximum test force of 2,000 kN. Given the high strength of the steels and their large dimensions, such a high test force was necessary to deform the material. The elongation of the plate was achieved by pulling a 12 mm thick sheet measuring 700 mm x 1000 mm until the defined strain was reached. To ensure a straight stop, edges were milled, and the sheets were mounted perpendicularly to the test direction to achieve an even force distribution during testing. Retroreflection stripes were applied at defined distances along the edges to measure elongation. During the process, the shift of the retroreflectors was measured using a laser, while the machine itself recorded the force. This method enabled the recording of the force-strain diagram throughout the entire process. The strain rate was adjusted to achieve both high strain just before necking and low strain conditions. The objective was to investigate the effects of cold forming by elongation and the subsequent development of coarse grain after welding.
Due to the different strain rates determined from the tensile tests, each material had specific maximum strain rates before necking occurred. Specifically, S700MC was tested at a strain rate of 3–9%, S960QL at 5%, and S1100 at 3%. Further elongation beyond these points led to necking and subsequent fracture.
Cold forming through bending was conducted using a folding machine, setting the inner radius to 56 mm, which was measured post-bending.
4.3. Welding of the cold formed steels
The elongated and bent specimens were joined using Gas Metal Arc Welding (GMAW). To investigate the deformed zone, a deformed sheet was joined with an unformed sheet of the same material. To ensure a straight line of the Heat Affected Zone (HAZ) and sufficient filler material for a stable connection, a HV-joint with an opening angle of 40° was employed. In this configuration, the straight side was the deformed side. To achieve consistent results between the sheets, welding was conducted using a robotic welding system.
The elongated plates were welded in the PA-position, while the bent plates were welded in the PC-position. The shielding gas used was M21 (18% CO2 and the remainder argon) to protect the weld seam. T8 − 5-times were measured directly in the melt using PT100 resistance. Preheating of the first layer was not necessary for S700MC. However, the higher-strength steels, S960QL and S1100, were preheated to 100°C. The intermediate and cover layers were then welded at 120°C. T8 − 5-times where between 8 and 10 seconds.
To fill the 12 mm plate, four layers were required, comprising of two filler layers and two cover layers. An additional layer was applied on the opposite side without preheating to ensure good root protection. To maintain strength and avoid degradation, steels were welded with filler materials of the same grade: Union X77 for S700MC and ED-FK1000 for the quenched and tempered steels (S960QL and S1100). Detailed welding parameters are provided in Table 3.
Table 3
material | parameter | root layer | filler layer 1 | filler layer 2 | cover layer 1 | cover layer 2 |
S700MC | speed [cm/min] | 25,5 | 40,8 | 51 | 51 | 51 |
voltage [V] | 17,7 | 23,7 | 23,7 | 23,7 | 23,7 |
current [A] | 170 | 290 | 290 | 290 | 290 |
S960Ql and S1100 | speed [cm/min] | 25,5 | 40,8 | 51 | 51 | 51 |
voltage [V] | 17,7 | 26,8 | 26,8 | 26,8 | 26,8 |
current [A] | 150 | 260 | 260 | 260 | 260 |
To verify the welding process, hardness tests via Ultrasonic Contact Impedance (UCI) were performed at the weld seams. Typically, the weld seam exhibits a characteristic hardness distribution. In structural steels, a loss of strength is common in the softened zone, which cannot be entirely avoided. Following this, there is a slight increase in hardness until the material returns to its normal strength comparable to the base material. Figure 4 illustrates the measurements taken on S700MC and S1100 after the welding process.
4.4. Positioning and extracting of the specimen
The specimens were extracted from the welded plates with a slight excess length. To accurately determine the notch position, the Heat Affected Zone (HAZ) was etched using 10% nitric acid (Nital) to make it visible. Due to this excess length, the notch was positioned in the recrystallization zone at the center of the specimen. Figure 5 demonstrates the notch position at the example of the straight sheet.
For the elongated sheets, samples could be taken along the entire length. In the case of bent sheets, samples were extracted from the area of greatest deformation, typically at the radius. This was achieved by cutting the sheets in half. Notched bar impact bending samples were then taken from the left side, while fracture mechanics samples were taken from the right side. The maximum size of the fracture mechanics samples was set at 10 mm to facilitate testing and ensure accurate evaluation.
4.5. Fracture mechanics
The CTOD (Crack Tip Opening Displacement) tests were conducted following ASTM E 1820 [23] and ASTM E1921 [24] standards, using SEB (Single Edge Bend) specimens with dimensions as recommended in these guidelines, as depicted in Fig. 6.
Initially, the specimens were pre-cracked under a stress ratio of 0,1, and the required force was determined accordingly. It took between 70.000 to 100.000 cycles to propagate the crack to a length of 0,4 to 0,7 times the specimen width (W). Following this, 1 mm deep side notches were milled into the specimens.
The tests were conducted in a temperature-controlled chamber using the single temperature method at -66°C. The span of the bend roller (S) was set to 80 mm. To ensure gradual loading and prevent impact, the force was applied slowly from the top at a rate of 0,3 mm/min. The stamp descended from above at the same rate of 0,3 mm/min until reaching a cut-off limit of 5 mm, controlled by path control. The test would automatically stop if a fracture was detected, defined by a 90% drop in force. Throughout the test, an extension sensor measured the displacement.
After fracture, annealing colors were generated on the specimen to aid in examining the residual fracture surfaces. To induce a brittle residual fracture surface, the samples were cooled in liquid nitrogen and subsequently fractured by impacting with a hammer. This helps to preserve the fracture surfaces in a brittle state, enabling detailed examination and analysis of the fracture characteristics. Images of the fractured surfaces were captured and analyzed using IC Measure software to determine the proportion of fatigue fracture versus residual fracture.
4.6. Notch impact test
For the notch impact test, a hammer with a energy of 300 J was applied. The specimens were V-notched according to DIN EN ISO 148 [22], with standard dimensions of 10x10x55 mm³ and a notch depth of 2 mm. The tests were conducted in alcohol baths cooled down to temperatures as low as -90°C. To reach even lower temperatures, nitrogen at -196°C was used. Higher temperatures were achieved by annealing the specimens in a furnace for a minimum of 10 minutes, ensuring uniform temperature throughout the sample. Immediately after removal from the temperature-controlled medium, the notch impact tests were performed. The resulting data pairs were plotted on a temperature-impact strength diagram. Typically, an S-curve characteristic of structural steels was fitted using an arctangent function. This fit was utilized to determine the characteristic value of T27J-temperatures, which represent the temperature at which the impact energy reaches 27J.