3.2 Hydro chemical indicators spatial variability pre and post monsoon (2013)
The maps that are provided show the pre-monsoon water quality for eight metrics within the research region. pH, Total Dissolved Solids (TDS), Calcium, Magnesium, Bicarbonate, Chloride, Electrical Conductivity (EC), and Total Hardness are among the parameters. Color gradients were utilized in each map to depict the concentration ranges of each parameter within the study area. The pH range of 7.04 to 7.54 indicated conditions that were neutral to slightly acidic (Fig. 4a). EC showed regions with high salinity levels up to 936.08 µS/cm, however it varied greatly (Fig. 4b). TDS concentrations ranged from 441.45 mg/l to other values (Fig. 4c). Regional differences were evident in the calcium and magnesium maps, with concentrations reaching up to 159.72 mg/l and 35.94 mg/l, respectively (Fig. 4d) and (Fig. 4e). The concentrations of chloride varied from 9.20 to 98.00 mg/l, whereas the amounts of bicarbonate ranged from 112.30 to 390.761 mg/l (Fig. 4f). Magnesium and calcium were included in the total hardness, which varied from 102.95 to 324.55 mg/l (Fig. 4e) and (Fig. 4d).
The post-monsoon water quality maps use color gradients to show different concentrations of eight important metrics throughout a study area. The range of pH values is from 7.25 to 7.83 (Fig. 5a) denotes a transition from slightly acidic to neutral conditions, implying that monsoon runoff and dilution have an impact on stable water chemistry. Higher values of Electrical Conductivity (EC) indicate greater ionic concentration from the leaching of minerals and salts. EC values range from 181.22 to 909.15 µS/cm (Fig. 5b). Concentrations of Total Dissolved Solids (TDS) range from 75.15 to 512.18 mg/l, which indicates a higher mineral composition as a result of surface runoff (Fig. 5c). Magnesium levels range from 8.83 to 22.16 mg/l, showing differing weathering rates. In contrast, calcium levels range from 24.48 to 193.16 mg/l, most likely due to the dissolution of calcium-bearing minerals (Fig. 5e) and (Fig. 5d). The range of bicarbonate concentrations (82.81 to 381.01 mg/l) indicates enhanced organic matter decomposition and chemical weathering (Fig. 4f). The range of chloride values, which are related to anthropogenic sources and soil leaching, is 17.70 to 89.93 mg/l. The range of 136.74 to 348.69 mg/l for total hardness indicated a considerable leaching of the minerals magnesium and calcium. (Fig. 4g) and (Fig. 4h).
3.3 Hydro chemical indicators spatial variability pre and post monsoon (2023)
The research area's pH values vary from 7.09 to 7.41 (Fig. 6a), with higher pH values indicated by deeper hues. With values ranging from 215.44 µS/cm to 828.38 µS/cm (Fig. 6b), EC varied greatly and indicated greater concentrations in some areas. Regions with values ranging from 107.83 mg/l to 417.17 mg/l (Fig. 6c). The geographical diversity of calcium, magnesium, bicarbonate, chloride, and total hardness highlights locations with varying concentration levels. These maps are essential for comprehending the distribution of pre-monsoon water quality, which aids in determining how the monsoon affects these factors.
There is a modest variance from the pre-monsoon levels to the post-monsoon pH levels, ranging from 6.97 to 7.39 (Fig. 7a)., with areas showing somewhat lower pH values. The current range of EC values, which show an increase in some locations compared to pre-monsoon, is 201.44 µS/cm to 1,059.10 µS/cm (Fig. 7b). This suggests that monsoon rains may have caused mineral leaching into the water. The range of TDS values has increased from 101.16 mg/l to 527.99 mg/l (Fig. 7c), suggesting greater concentrations in certain regions during the monsoon. The range of calcium levels has changed from 36.64 mg/l to 57.95 mg/l, with considerable increases in some areas and the current range of magnesium concentrations is 5.40 mg/l to 59.08 mg/l, with a rise in higher concentration zones (Fig. 7d) and (Fig. 7e). The range of bicarbonate levels is 91.62 mg/l to 337.61 mg/l (Fig. 7f), with notable elevations in specific regions. The amounts of chloride have also gone up, from 20.28 mg/l to 121.81 mg/l and beyond monsoon, total hardness, which ranges from 139.57 mg/l to 416.16 mg/l, has a more widely distributed range of greater concentrations. (Fig. 7g) and (Fig. 4h).
3.4 Drawdown spatial variability pre and post monsoon (2013–2023)
Four maps that show the groundwater drawdown levels in a study region under various conditions and time periods are included in the (Fig. 8). For the years 2013 and 2023, the pre-monsoon and post-monsoon regions are represented on each map, respectively. The drawdown levels in 2013 before the monsoon season are depicted in (Fig. 8a), where the decline ranges from 5.77 to 10.08 meters. It displays different groundwater levels in different locations (5.77–7.26 meters) and higher levels of drawdown (8.30–10.08 meters) in different regions. This shows varying groundwater levels in 2013 prior to the monsoon season. The drawdown levels following the 2013 monsoon season are shown on (Fig. 8b), which ranges from 5.95 to 9.71 meters. Following the monsoon, different locations suffer different amounts of decline. In certain places, there is less drawdown (5.95–7.31 meters), perhaps because of groundwater recharge from the monsoon rains, while in other parts, there is still more drawdown (8.35–9.71 meters). (Fig. 8c), shows the drawdown levels in 2023 before to the monsoon season, spanning a wider range from 3.28 to 13.35 meters. Groundwater levels are more variable now than they were in 2013, with some regions seeing much less decline (3.28–6.95 meters) and others seeing substantially more drawdown (9.36–13.35 meters). This may suggest that groundwater levels have been more variable during the past ten years.
3.5 Temporal variability of water quality and drawdown pre and post monsoon (2013–2028)
An examination of water quality measures from 2013 to 2028 is shown in the (Fig. 9), which highlights significant trends and changes. Electrical conductivity (EC) varied a lot; it was around 500 µS/cm in 2013, dropped to 400 µS/cm in 2021 (Fig. 9a), and then increased once again. Total Dissolved Solids (TDS) showed a similar trend, peaking at roughly 450 mg/L in 2013 and falling to 350 mg/L in 2021 before rising again (Fig. 9a). These variations point to possible sources of contamination as well as shifts in ion concentration. With very slight fluctuations, total hardness was comparatively constant at 250 mg/L, suggesting steady levels of calcium and magnesium ions two essential elements for preserving the quality of water. While pH measurements continuously stayed around 7.5 (Fig. 9a), suggesting steady acidity/basicity, bicarbonate levels, which contribute to alkalinity, remained stable at 150 mg/L. Magnesium levels were constant at around 20 mg/L, whereas calcium levels fluctuated slightly at 60 mg/L (Fig. 9a). The amount of chloride in the water dropped from around 350 mg/L in 2013 to about 300 mg/L in 2021 (Fig. 9a), and then it stabilized, indicating either a shift in pollution levels or better water management techniques. These patterns emphasize how crucial it is to preserve water quality and deal with possible sources of pollution through ongoing monitoring and efficient management. Many of the services that are provided by the ecosystems of the world are essential to our day-to-day lives. Groundwater ecosystems provide a number of services provide that are of tremendous societal and economic importance. These services include the purification of water and the storage of water in superior quality for decades and millennia (Griebler and Avramov, 2015).
The graph shows how several water quality measures vary over time during the post-monsoon period, from 2013 to 2028. Critical indicators of water quality include pH, Calcium, Magnesium, Chloride, Total Dissolved Solids (TDS), Total Hardness, Bicarbonate, and Electrical Conductivity (EC). EC values are not constant; they typically increase to about 400 µS/cm by 2028 after declining from 450 µS/cm in 2013 to around 350 µS/cm in 2020 (Fig. 9b). High EC may be a sign of salinity, which can affect soil health and agricultural productivity. TDS levels have an impact on the flavor and acceptability of the water for drinking and irrigation. They decreased dramatically from around 300 mg/L in 2013 to approximately 200 mg/L in 2016 (Fig. 9b), then increased roughly to 250 mg/L by 2028. Total hardness has a slight fluctuating influence on soap efficacy and scale development, falling from around 350 mg/L Ca in 2013 to approximately 250 mg/L Ca by 2016 (Fig. 9b). Between 180 and 220 mg/L, bicarbonate remains stable and is essential for pH stability and buffering capabilities. The pH scale, which is necessary for aquatic life and metabolic activities, increases slightly from 7.0 in 2013 to 7.5 by 2028 (Fig. 9b). Magnesium levels vary from 20 to 25 mg/L, whereas calcium levels range from 20 to 30 mg/L, which contributes to water hardness. Between 2013 and 2016, chloride levels drop from about 300 mg/L (Fig. 9b) to about 200 mg/L, stabilizing after that. Increasing chloride levels seen after 2022 indicated a heightened degree of human activity. Another factor that contributed to the regulation of the hydro geochemistry of groundwater in this region is the agricultural activities that take place during the monsoon seasons (Natesan et al., 2022).
Pre- and post-monsoon groundwater drawdown analyses are shown on the graph, along with yearly rainfall data from 2013 to 2028. Before the monsoon, the drawdown varied from about 8.1 to 8.7 meters (Fig. 9c),. Pre-monsoon drawdown is represented by the regression equation
$$\:\text{Y}=-0.00001\text{X}+8.351$$
1
which shows an annual decrease of around 0.0095 meters (Fig. 9c),. This shows that groundwater levels have been gradually declining over time prior to the monsoon season. On the other hand, the post-monsoon decline was between 7.6 and 7.8 meters (Fig. 9c),. The post-monsoon drawdown regression equation is
$$\:\text{Y}=-0.0095\text{X}+7.964\:\:\:$$
2
demonstrating a very steady groundwater level following the monsoon with a minor yearly reduction of 0.00001 meters. The yearly rainfall data did not exhibit a discernible pattern throughout the time, with variations ranging from 200 to 400 millimeters. Regression analysis showed that the pre-monsoon drawdown significantly decreased while the post-monsoon drawdown remained almost constant. This implies that recharge from monsoon rains does not sufficiently offset the pre-monsoon groundwater depletion.
XGBoost was consistently the best-performing model, according to a comparative investigation of predictive models for drawdown and groundwater quality.After analyzing the results of statistical indicators (MAE, RMSE AND R2) shows that XGBoost consistently produced the highest R² values for groundwater quality indicators, including pH, Electrical Conductivity (EC), Total Dissolved Solids (TDS), Calcium, Magnesium, Total Hardness, Bicarbonate, and Chloride. These results indicate XGBoost's superior capacity to explain the variance in the data. Furthermore, XGBoost demonstrated the lowest RMSE and MAE values among these metrics, indicating its great prediction accuracy and precision. For instance, in predicting pH, XGBoost maintained the lowest RMSE (0.09) and MAE (0.06) and attained a R² of 0.89 (Table 3), which was much greater than the other models. Similarly, XGBoost again distinguished itself by having the highest R² (0.86) in the prediction of the link between groundwater drawdown and rainfall, indicating its resilience in capturing this relationship. Additionally, it showed the lowest MAE (0.053) and RMSE (0.072) (Table 3), demonstrating the precision and dependability of its forecasts.
On the other hand, compared to XGBoost, the other models like Support Vector Machine (SVM), K-Nearest Neighbours (KNN), and Random Forest (RF) always had lower R2 values and greater RMSE and MAE values across all parameters. Consequently, XGBoost was found to be the most accurate model for predicting groundwater quality and drawdown based on this thorough examination, making it an extremely dependable tool for managing water resources and the environment.
Table 3
Comparative performance of predictive models in groundwater quality and drawdown prediction: evaluating R², RMSE, and MAE metrics
Evaluation Parameter | SVM | KNN | RF | XGBoost |
pH (R2) | 0.74 | 0.78 | 0.82 | 0.89 |
pH (RMSE) | 0.12 | 0.11 | 0.1 | 0.09 |
pH (MAE) | 0.09 | 0.08 | 0.07 | 0.06 |
EC (R2) | 0.76 | 0.77 | 0.81 | 0.85 |
EC (RMSE) | 0.11 | 0.1 | 0.09 | 0.08 |
EC (MAE) | 0.08 | 0.07 | 0.06 | 0.05 |
TDS (R2) | 0.75 | 0.76 | 0.8 | 0.84 |
TDS (RMSE) | 0.11 | 0.1 | 0.09 | 0.08 |
TDS (MAE) | 0.08 | 0.07 | 0.06 | 0.05 |
Calcium (R2) | 0.75 | 0.77 | 0.81 | 0.85 |
Calcium (RMSE) | 0.11 | 0.1 | 0.09 | 0.08 |
Calcium (MAE) | 0.08 | 0.07 | 0.06 | 0.05 |
Magnesium (R2) | 0.75 | 0.77 | 0.81 | 0.85 |
Magnesium (RMSE) | 0.11 | 0.1 | 0.09 | 0.08 |
Magnesium (MAE) | 0.08 | 0.07 | 0.06 | 0.05 |
Total Hardness (R2) | 0.75 | 0.77 | 0.81 | 0.85 |
Total Hardness (RMSE) | 0.11 | 0.1 | 0.09 | 0.08 |
Total Hardness (MAE) | 0.08 | 0.07 | 0.06 | 0.05 |
Bicarbonate (R2) | 0.75 | 0.77 | 0.81 | 0.85 |
Bicarbonate (RMSE) | 0.11 | 0.1 | 0.09 | 0.08 |
Bicarbonate (MAE) | 0.08 | 0.07 | 0.06 | 0.05 |
Chloride (R2) | 0.75 | 0.77 | 0.81 | 0.85 |
Chloride (RMSE) | 0.11 | 0.1 | 0.09 | 0.08 |
Chloride (MAE) | 0.08 | 0.07 | 0.06 | 0.05 |
Rainfall and Drawdown (R2) | 0.75 | 0.68 | 0.82 | 0.86 |
Rainfall and Drawdown (RMSE) | 0.102 | 0.125 | 0.083 | 0.072 |
Rainfall and Drawdown (MAE) | 0.076 | 0.089 | 0.061 | 0.053 |