Tuning the anionic solvation structure and dynamic processes at solid‒liquid interfaces are critical yet challenging for stabilizing Zn metal anodes in Zn ion batteries. Here, we demonstrate that highly hydrated SO42− can be modulated under a strong magnetic field (MF) via the Paschen-Back effect on the O-H stretching mode, which reorients individual water molecules to manipulate Zn²⁺ solvation and protonated water clusters (H3O+). This high level of hydration was confirmed through Raman spectroscopy, molecular dynamics (MD) simulations, and ¹⁷O/¹H nuclear magnetic resonance (NMR) with coaxial insert tubes. Our findings reveal that the MF disrupts the hydrogen-bonded water structure (DDAA), leading to charge redistribution and localization onto the SO42− -4H₂O (DDA) complex, inhibiting the intra-molecular Fermi resonance of free O-H stretch water (DAA-OH) and suppressing the Zn2+-6H₂O interaction. Additionally, MD simulations and electrochemical characterizations show that these hydrated SO42−-H₂O complexes favor Zn2+ nucleation and deposition on the (002) plane, with the preferential adsorption of oxygen on Zn (002) inhibiting 2D Zn2+ diffusion. Combined with density functional theory (DFT) analysis, we demonstrate that magnetically treated ZnSO4 electrolytes exposed to a 3 T MF for 25 minutes can disrupt the Grotthuss proton-transport mechanism, suppressing H2 evolution and achieving 100% dendrite-free growth. This work highlights the critical role of magnetization pretreatment in enhancing the stability of electrochemical interfaces, offering insights for the molecular design of interfacial water in various aqueous Zn-based batteries.