An Innovative Method for the Sustainable Utilization of Blast-furnace Slag in the Cleaner Production of One-part Hybrid Cement

doi:10.21203/rs.3.rs-581722/v1

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An Innovative Method for the Sustainable Utilization of Blast-furnace Slag in the Cleaner Production of One-part Hybrid Cement

https://doi.org/10.21203/rs.3.rs-581722/v1

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Hybrid cement (HC) can be defined as alkali activated-blended-Portland cement (PC). It was prepared by the addition of an alkaline solution to high-volume aluminosilicate-blended-PC. Although this cement exhibits higher mechanical performance compared to conventional blended one (aluminosilicate-PC blend), it represents lower commercial viability because of the corrosive nature of an alkaline solution. Therefore, this study focuses on the preparing one-part-HC using dry activator-based blast-furnace slag (DAS). DAS was prepared by mixing sodium hydroxide (NaOH) with blast-furnace slag (BFS) at low water to BFS ratio, followed by drying and grinding to yield DAS-powder. Different contents of DAS (equivalent to 70 wt.% BFS and 1, 2, and 3 wt.% NaOH) were blended with 30 wt.% PC. A mixture containing 70 wt.% BFS and 30 wt.% PC was used as a reference sample. The mortar was adjusted at sand: powder (BFS-PC and/or DAS-PC) weight ratio of 3: 1. The microstructural analysis proved that DAS-powder is mainly composed of sodium calcium aluminosilicate activated species and unreacted BFS. These species can interact again with water to form calcium aluminum silicate hydrate (C-A-S-H) and NaOH, suggesting that the DAS acts as NaOH-carrier. One-part HC-mortars having 1, 2, and 3 wt.% NaOH recorded 7-days compressive strength values 82, 44, and 27 %, respectively, higher than that of the control sample. At 180-days of curing, a significant reduction in compressive strength was observed within HC-mortar having 3 wt.% NaOH. This could be attributed to the increase of Ca (within C-S-H) replacement by Na, forming Na-rich-phase with lower binding capacity. The main hydration products within HC are C-S-H, C-A-S-H, and chabazite as one of zeolite family.

Medical Physics

Materials Chemistry

Blast-furnace slag

Sodium hydroxide

Chabazite

Activated species

Compressive strength

Portland cement (PC) is the common and dominant binding material in the construction sector [1, 2]. Almost 4 billion tonnes is the annual production of PC worldwide, since China produces more than a half of global cement production [3, 4]. About 8% of the total anthropogenic global warming potential is resulted from PC-manufacturing [5]. Each metric tonne of PC requires 4.2 GJ energy, releasing approximately in 0.8-1.0 tonne of carbon footprint into surrounding environment [6]. To mitigate the high CO₂ emission and energy demand, several authors replaced a high portion of PC by supplementary cementitious materials such as fly ash (FA), silica fume (SF), and blast-furnace slag (BFS) [7–11]. Although the role of supplementary cementitious materials in the mitigation of carbon footprint and the improvement of the durability and the later mechanical properties of PC [12–17], the substitution of PC with high volume of these materials caused a noticeable retardation in its early hydration [18–20].

BFS is simply defined as a calcium aluminosilicate rich-waste resulted from the top of smelted iron during the heating of iron ore in a blast furnace. The molten BFS was quenched with water to yield glassy materials with high amorphous content [21]. Statistically, the extraction of 1 tonne of iron from ore generates almost 0.3 to 1.0 tonne BFS [22]. It is well known that BFS was used as a partial substituent to PC to yield what is called as slag cement [23]. Several authors stated that the replacement of PC by high volume BFS has reflected on a significant reduction of the heat of hydration, resulting in a retardation in the early compressive strength [24–26]. It was found that the performance and hydration characteristics of PC-BFS cement enhanced with increasing the curing temperature and the fineness of slag [27–29].

The addition of nano silica led to a significant improvement in the early compressive strength accompanied by an acceleration in setting time of high volume BFS blended cement [30–33]. A considerable improvement (16%) in the compressive strength of high volume BFS blended cement was achieved by the addition of 1 wt.% nano alumina [34]. the positive role of silica and alumina nano-particles is mainly originated from the formation of the additional calcium silicate hydrate (C-S-H), ettringite and calcium aluminate hydrate (C-A-H), which have high efficiency in the mechanical properties improvement and the pore size reduction [30–34]. Other study [35] proved that the addition of 1 to 4 wt.% nano calcium carbonate to cement paste individually containing 70, 80, and 90 wt.% BFS led to the enhancement of their strengths by 8 to 24%, 1 to 16% and 2 to 20%, respectively.

As an innovative approach, the addition of alkalis to high volume BFS-blend-PC has resulted in the formation of the alkali-activated BSF-PC, namely hybrid cement (HC) [36, 37]. The individual addition of sodium hydroxide (NaOH) and sodium silicate (Na₂SiO₃) to PC containing 80 wt.% produced hardened materials with compressive strength value 4.5 and 10.8 times, respectively, higher than that BFS-PC blend [38]. After dissolving alkali, it should be kept for enough time to cool before its mixing with BFS-PC blend. The corrosive nature of alkaline solutions [39] is the common reason behind the retardation of the commercial viability of this type of cement. It is important to produce hybrid cement, in which alkali incorporated inside its composition. In other word, one-part-HC (just added water) should be prepared to achieve the safe use of this type of cement.

Therefore, this paper focused on the utilization of dry activator-based alkali activated BFS (DAS) in preparing one-part hybrid alkali-activated slag-PC. DAS was prepared by mixing sodium hydroxide solution with BFS (at low water to powder ratio of 0.1), followed by drying and grinding to yield DAS-powder, which acts as a safe and stable NaOH-carrier. The ability of sodium leaching from DAS into surrounding media was evaluated using pH measurement. The impact of sodium oxide content within dry activator on the performance of HC composed of 70 wt.% BFS and 30 wt.% PC was evaluated. This study also suggested the hydration reaction mechanism and the composition of strength-giving-phases resulted from one-part-HC.

2.1. Materials resources

One-part hybrid cement (HC) mortar was fabricated from sand, ordinary Portland cement (OPC), blast-furnace slag (BFS), and sodium hydroxide (NaOH). Sand was brought from El-Wasta area (Beni Suef, Egypt). OPC (type I: 42.5 N) was purchased from Beni-Suef Cement Company (Cairo, Egypt). BFS was supplied from Helwan Company for Steel Industry (Helwan, Egypt). NaOH with purity of 99.99% was imparted by LOBA Chemical Company (India). Table 1 shows the chemical oxides compositions of OPC, BFS, and sand. X-ray diffraction (XRD) analysis (Fig. 1) proved that BFS exhibits a completely amorphous pattern with a hump at 2theta of 20–35º. OPC and BFS demonstrated specific surface areas of 3410 and 3540 cm²/g, respectively.

2.2. Preparation of one-part hybrid cement powder

One-part hybrid cement powder was synthesized by mixing dry activator based alkali activated slag (DAS) with OPC. DAS was prepared by activating the BFS with NaOH solution, followed by drying and grinding. As shown in Table 2, BFS was individually activated by 1, 2, and 3 wt.% NaOH at W/BFS ratio of 0.1. The activated slurry immediately dried at 80 ºC for 24 h, followed by grinding to yield DAS-powder. The W/BFS ratio of 0.1 was chosen according to previously published work [40], which reported that W/BFS ratio of 0.1 is appropriate water content for the formation of alkali-activated powder with high capability to re-interact with water, yielding hardened materials. One-part-HC was prepared by mixing DAS with OPC at different weights equivalent to 70 wt. % BFS and 1, 2, and 3 % NaOH (by weight of BFS). Control sample containing 70 wt.% BFS and 30 wt.% OPC was made for comparison. The details of mixing proportions were listed in Table 3.

Table 1

Chemical oxides compositions of the starting raw materials
Samples notations	Chemical compositions, wt. %
Samples notations	SiO₂	CaO	MgO	Fe₂O₃	Al₂O₃	Na₂O	K₂O	Cl	SO₃	P₂O₅	TiO₂	LOI
OPC	21.01	63.15	2.45	3.36	5.09	0.37	0.07	0.04	2.69	-	-	1.82
BFS	41.51	34.58	4.59	0.57	13.38	1.94	0.86	0.06	1.73	0.32	0.43	-
Sand	94.38	-	-	1.21	2.17	0.12	0.09	0.03	0.09	0.02	0.04	0.13

Figure 1. XRD-pattern of blast-furnace slag (BFS)

Table 2

Compositions of the prepared dry activator based slag (DAS)
Dry activator notations	BFS	NaOH	Water content	Theoretical Wt. of DAS	Actual Wt. of DAS	NaOH within DAS powder	BFS, within DAS powder	Combined water within DAS powder
	Weight (gram)					Wt. %
DAS-1	100.00	1.00	10.00	111.00	103.18	0.97	96.91	2.11
DAS-2	100.00	2.00	10.00	112.00	105.48	1.90	94.80	3.30
DAS-3	100.00	3.00	10.00	113.00	106.51	2.82	93.88	3.41

Table 3

Weights of BFS, OPC, and DAS within one-part-HC
Mixtures notations	BFS	OPC	DAS	Weight of BFS within DAS	Weight of NaOH within DAS
Mixtures notations	Weight (gram)
Control	70.00	30.00	-	-	-
HC-DAS-1	-	30.00	72.23	70.00	0.70
HC-DAS-2	-	30.00	73.84	70.00	1.40
HC-DAS-3	-	30.00	74.56	70.00	2.10

3.3. Preparation of one-part-HC mortar

One-part-HC mortar was designed at sand: powder (BFS-OPC and/or DAS-OPC) weight ratio of 3:1. Sand and powder were dry mixed in a ball mill; after that the dry blend was transferred to mixer, then the water was added (at W/P ratio of 0.47). Slow and rapid rates of wet mixing were applied on the fresh cement mortar to ensure the complete homogeneity. The workable mortar was transferred into stainless steel molds with dimensions 50 x 50 x 50 mm, followed by vibration, smoothing, and curing in relative humidity of 99 ± 1% at 23 ± 2 ºC for 24 h. Thereafter, the hardened mortar was demolded and cured under tap water for 7, 28, 90, and 180 days. Cement paste with the same BFS-OPC and DAS-OPC weight ratios were prepared for investigating the hydration products.

3.4. Experimental methods

Different experimental methods, including flowability, setting time, zeta potential, and compressive strength, were carried out on the prepared one-part-HC-paste and/or mortar. The workability of the fresh one-part-HC-mortar and BFS-OPC-mortar was determined by measuring the average spread diameters of the fresh mortar on flow the table [41]. Initial and final setting times of the fresh pastes were conducted three times on each mixture using Vicat apparatus based on ASTM C191 [42]. Zeta potential of the fresh cement mortars was measured using Malvern Zetasizer (nano-series), in which deionized water was used as a carrier liquid. This test was conducted to determine electrostatic repulsion between hydrated cement particles within cement mortar. Compressive strength of the hardened one-part-HC-mortar was measured according ASTM C109M [43] using German-Bruf-Pressing Machine with a maximum load capacity of 175kN. This test was conducted on three-hardened cubes of each mixture and the average reading was recorded. The broken paste was crushed and washed several times using acetone and methanol solution (at volume ratio of 1:1), then dried at 70 ºC for 3 h, to stop the hydration reaction. After that, the dried paste was kept in a vessel until analyses. In contrast, the broken cement mortar was immersed in the same solution for 24 h, followed by drying at 70 ºC for 3 h, and then kept until microstructural investigation.

3.5. Instrumental techniques

pH of the prepared DAS was conducted on the filtrate of the suspended solution (at DAS to distilled water weight ratio of 0.5) via Delta OHM HD 8705 pH meter and PCFC11 combination electrode with accuracy of 0.01. This test was conducted three times and the pH value was accepted if the variation rate of reading was less than 0.01 / minute. The oxides compositions of the starting materials were determined using X-ray fluorescence spectrometer (XRF: Xios, PW1400). The mineralogical compositions of the hardened cement pastes was identified using X-ray diffraction (XRD). This analysis was conducted on the powdered-sample of the hydrated cement pastes using Philips PW3050/60 diffractometer. The mineralogical compositions were determined within the 2theta range of 5–50º with 1s/step scanning rate and 0.05°/step resolution. Thermogravemetric analysis and its derivative (TG/DTG) was performed using DT-50 Thermal Analyzer (Schimadzu Co-Kyoto, Japan). This analysis was carried out on the powdered-cement paste to identify the hydration phases within its matrix. Each weight loss appeared at definite temperature is affiliated to the specific hydration product. This test was conducted by weighing 20 mg of sample in Pt-crucible, then heated in N₂ atmosphere up to 1000 ºC and heating rate of 10 ºC / min. The functional groups within hydration products were identified using Fourier transform infrared (FT-IR) spectroscopy (KBr-discussing Genesis-II FT-IR spectrometer) at the wavelength range of 400–4000 cm^− 1. The microstructural development of the hardened one-part-HC-mortar was investigated using field emission scanning electron microscopy (FESEM, FEI Company, Holland) provided by an energy dispersive X-ray analyzer (EDS).

3.1. Characterization of DAS

The characterization of DAS is very important to determine its reaction mechanism and its role in the hydration of one-part-HC. FESEM-micrographs (Fig. 2) show that the addition of NaOH to BFS during preparing DAS has resulted in a partial dissolution of polygonal-shaped-BFS particle to form sodium calcium aluminosilicate species as confirmed by EDS-analysis. Additionally, the formation of these species enhances with NaOH addition.

As stated by Davidovits [44], gehlenite and akermanite within BFS can be dissolved by NaOH to yield (Na, Ca)-ortho-sialate hydrate and calcium silicate hydrate as activated species. After that, these species condense together to form (Na, Ca)-cyclo-ortho-(sialate-disiloxo) and excess of calcium silicate hydrate (Fig. 3). Polymerization process is the following step, in which a long chain of sodium calcium aluminosilicate is formed. The mixing water content plays an important role in the dissolution/condensation process [45]. As prviousely stated [40], the use of low water during activation process plays a circular role in the control of condensation rate. The addition of low water content, followed by drying, causes a retardation in the condensation process, forming DAS with high activated species content. This is the main reason behind the justification of mixing water at W/BFS ratio of 0.1 and the application of drying during preparing DAS.

To identify the reactivity of activated species, the leaching test was applied to the prepared DAS. As shown in Fig. 4, a significant rising in pH-value in a short time (5 minutes) was recorded after suspension of DAS-powder in water. The possible explanation of this outcome is the moving Na cation at the ortho position within activated species, forming sodium hydroxide in the water medium (Fig. 5). This means the high hydraulic reactivity of DAS, as the activation process can be continued after water addition. It can be said that the DAS acts as a carrier of NaOH, which strongly contributes to resolve the corrosive nature of alkali solutions during preparing one-part-HC.

3.2. Flowability and zeta potential of one-part-HC-mortars

The impact of NaOH contents within DAS on the workability and zeta potential of fresh one-part-HC mortar is represented in Fig. 6. Generally, the spreading diameter of the fresh HC-mortars indicates their workability. The fresh HC-mortar with the broadest speeding diameter exhibits the best fluidity. There is a direct relationship between the flowability of the mortar and the negative zeta potential values. Increasing the NaOH content within DAS leads to a significant enhancement in the workability, which coincides with an increment in negative zeta potential value, as in line with the previously published work [46], which stated that the addition of Na₂O content enhances the workability of one-part alkali activated cement. He et al. [47] proved that increasing negative zeta potential is mainly originated from an increment in the electrostatic repulsive force between cement particles, resulting in an enhancement in the workability of the fresh cementitious material.

3.3. Setting time of one-part-HC pastes

The initial and final setting times (IST and FST, respectively) of the fresh BFS-OPC and DAS-OPC pastes are shown in Fig. 7. The setting time of the fresh cement paste mainly depends on the content of NaOH within DAS. Depending on the composition of the fresh cement pastes, the IST was identified after 183-264 minute; meanwhile, the FST was recorded after 275-367 minute. One-part HC samples record shorter IST and FST compared to BFS-OPC blend. The setting time decreases toward control > HC-DAS-1 > HC-DAS-2 > HC-DAS-3. This means that increasing NaOH content has a significant effect on the dissolution of aluminosilicate and the formation of binding phases [48].

3.4. Phase identification

The XRD-patterns of the BFS-PC blend (reference sample) and one-part HC-pastes hydrated for 7 and 28-days are shown in Fig. 8. Portlandite (Ca(OH)₂), C-S-H, calcite, and ettringite are the main phases within control sample. Beside (Ca(OH)₂), C-S-H, calcite peaks, chabazite (calcium sodium aluminum silicate hydrate: C-N-A-S-H) and gypsum were identified within the patterns referred to one-part HC-pastes. For both control and one-part HC-DAS-2 mixtures, increasing curing times from 7 up to 28 days results in a significant depletion of Ca(OH)₂accompanied by an enhancement in C-S-H growth. This confirmed the improvement of pozzolanic rate with time advanced, similar to the previous works [49-51]. Nevertheless, one-part HC-DAS-2 demonstrated the highest Ca(OH)₂consumption and C-S-H formation rates. Increasing NaOH content up to 3 wt.% within DAS has resulted in a significant increment in C-S-H formation at the expense of Ca(OH)₂phase. This confirms the fact that the activated aluminosilicate species within DAS can easily interact with Ca(OH)₂to yield C-S-H and/or C-N-A-S-H binding phases [52-55]. Ettringite has been detected within the pattern affiliated to control sample at 7-days of hydration. With time advanced up to 28 days, ettringite peaks disappeared. This confirmed the dissociation of ettringite with curing time, as in agreement with previous reports [23, 56]. On the other hand, the presence of alkali within one-part HC-paste prevents the formation of ettringite. This could be the possible reason behind the appearance of gypsum within the hydrated one-part HC pastes. Halaweh [57] stated that the presence of alkali increases the rate of sulfate release into solution, causing instability of ettringite.

Fig. 9 represents the TG/DTG-curves of BFS-OPC blend and one-part-HC hydrated for 7 and 28-days. All peaks are mainly related to the weight loss of the hydration phases within hardened pastes. The compositions of the hydration products strongly depend on the temperature at which the peak appeared. The peaks appeared at the temperature range of 50-200 ºC are mainly affiliated to the dehydration of combined water within C-S-H, C-A-S-H, and/or C-N-A-S-H [58, 59]. Other peaks at 487 ºC are related to the decomposition of Ca(OH)₂ [60, 61]. The peaks referred to the decarbonation of CaCO₃ were identified at a temperature range of 600-800 ºC [62, 63].

For BFS-OPC and one-part HC-DAS-2 mixtures, increasing curing time causes an enhancement in the intensity of C-S-H, C-A-S-H and/or C-N-A-S-H peaks at the expense of Ca(OH)₂. This perfectly highlights the fact that the activation, hydration, and pozzolanic reactions are ongoing with time advanced. Comparing with the reference sample, the HC-DAS-2 mixture demonstrates the higher C-S-H, C-A-S-H and/or C-N-A-S-H peaks intensity at 7 and 28 days of curing. This confirms the positive role of Na₂O within DAS in the acceleration of the pozzolanic reaction and the formation of excessive binding-phases content. As aforementioned, the DAS is mainly composed of reactive sodium calcium aluminosilicate species. These activated species can hydrate and interact with Ca(OH)₂, to yield binding-phases easier than gehlenite and akermanite mineral within BFS. Increasing NaOH content up to 3 wt.% (HC-DAS-3) enhanced the formation of C-S-H, C-A-S-H and/or C-N-A-S-H accompanied by a significant consumption of Ca(OH)₂. These outcomes agree with XRD-results.

3.5. Compressive strength

The compressive strength values of the hardened BFS-OPC and one-part-HC-mortars are graphically represented in Fig. 10. Increasing curing time (up to 180 days) was found to have a positive impact on the compressive strength development. This means the successive formation of strength-giving-phases (C-S-H C-A-S-H, and/or C-N-A-S-H) with time advanced as confirmed by XRD and TG/DTG analyses. Same trend was observed in the previously published reports [37, 64-65]. Increasing NaOH content within DAS up to 2 wt. % materially improves the early compressive strength (at 7-days). The NaOH-content beyond 2 wt.% reduces 7-days compressive strength, but still higher than that of the control sample (BFS-OPC). One-part-HC-mortars individually containing DAS-1, DAS-2, and DAS-3 exhibit 7-days compressive strength ~ 44, 77, and 27 %, respectively, higher than that of the hardened BFS-OPC mortar. At later ages (28 to 180-days), the HC-DAS-1 and HC-DAS-2 show the same trend. The hardened HC-DAS-3 achieves later compressive strengths lower than those of the control sample. This proves the fact that the NaOH-content released from DAS (Fig. 5) plays an important role in the performance of one-part HC-mortar.

Cement hydration and alkali BFS activation are the two synergistic mechanisms of one-part HC-mortar. The activated aluminosilicate species-containing-DAS interacts with water to yield C-A-S-H and NaOH (Fig. 5). The unreacted BFS within DAS was dissolved by the liberated NaOH through alkali-activation process, yielding C-N-A-S-H, as confirmed by XRD-analysis (Fig. 8). On the other hand, the OPC within one-part HC-mortar also interacts with water to produce C-S-H and Ca(OH)₂. An additional C-N-A-S-H could be formed through the consumption of Ca(OH)₂ by the activated species resulted from alkali BFS-activation. In contrast, the formation of strength-giving-phases is resulted from the pozzolanic reaction, as C-S-H and/or C-A-S-H, was formed through the interaction between aluminosilicate within BFS and Ca(OH)₂ resulted from OPC hydration.

It is recognized that the enhancement of hydration products’ content strongly reflects on the mechanical properties of the hydrated cement [40, 46, 58, 66, 67]. Accordingly, a relationship between compressive strength and hydration products content (determined by TG-analysis) within cement pastes hydrated for 28-days was represented in Fig.11. Increasing NaOH content (up to 2 wt. %) enhances formation of the hydration products and compressive strength. Although the hydrated sample having 3 wt. % exhibits the highest hydration products content, it demonstrated compressive strength value lower than those of other HC-mixtures and control sample. These variations in outcomes confirm the fact that the DAS with appropriate Na₂O content should be prepared to achieve the high performance of one-part HC.

As suggested by Shi et al. [68], the Na₂O could interact with C-S-H through different three mechanisms. The neutralization of acidic silanol group (Si-OH) is the possible first reaction. The second mechanism includes the partial replacement of Ca ion in C-S-H to yield N-C-S-H. Meanwhile, the third mechanism is the formation of Si—O^-Na⁺ through the complete destruction of the binding capacity of C-S-H. It can be said that these mechanisms mainly depend on the content of Na₂O in the cement matrix. The first and second mechanisms happen in the presence of relatively low Na₂O content; whereas the third occurs at the high Na₂O content. For HC-DAS-1 and HC-DAS-2 mixtures, the appropriate Na₂O-content leads to the formation of N-C-A-S-H accompanied by compressive strength development. Conversely, a competition between second and third mechanism could happen in with HC-DAS-3 mixture, resulting in the formation of hydration products with lower binding capacity compared with those of other samples.

3.6. Microstructure

Fig. 12 displayed the FESEM-micrographs and elemental EDS-patterns of control and one-part HC-mortars. For BFS-OPC and HC-DAS-2 mixtures, increasing curing time from 7 up to 28-days enhanced the compaction of microstructure and the formation of binding phases, confirming the compressive strength results. At 7-days of curing, the flakey-shaped-phase is the dominant hydration product within BFS-OPC mixture. With time advanced (up to 28-days), this phase transformed to interconnected fiber-shaped-phase. The EDS-analysis confirmed that these phases (flakey- and fiber-shaped-phases) are mainly affiliated to C-S-H and/or C-A-S-H. No transformation in the morphology of hydration products has been detected with curing time of HC-DAS-2. Nonetheless, increasing curing time caused an enhancement in the formation of needle-C-S-H and rhombohedral zeolitic chabazite (C-N-A-S-H) crystals, as proved by EDS-analysis. This is in line with XRD-results. Additionally, same morphology of chabazite phase has been identified in the previously published works [69-71]. Finally, needle-shaped-crystals and minor of rhombohedral-chabazite-crystals were distributed on gel-like phase within the microstructure of HC-DAS-3 mixture hydrated for 28-days. These variations in the microstructural development and the morphology of the hydration products proved the role of Na₂O content in the mechanical performance of the prepared one-part HC-mortars. Therefore, a relationship between Na/Ca ratio (identified by EDS-analysis) and 28-days compressive strength values of one-part HC-mortar was represented in Fig. 13. Increasing the NaOH within DAS induces the incorporation of Na into the hydration products. In other words, the replacement of Ca within C-S-H and/or C-A-S-H enhanced with NaOH addition. Interestingly, the best 28-days compressive value was recorded at Na/Ca mole ratio of 0.11. Whereas a significant regression in compressive strength values was achieved when the NaOH content within DAS increases up to 3 wt.%.

This paper reported the synthesis and characterization of one-part hybrid cement mortar, in which dry activator-based blast-furnace slag and Portland cement were the main ingredients. Dry activator with different contents were blended with Portland cement to achieve 70 wt.% blast-furnace slag and 1, 2, 3 wt.% NaOH. The hydrated one-part hybrid cement mortar containing 1 and 2 wt.% NaOH was found to exhibit shorter setting time, higher workability, and higher compressive strength compared to blended cement containing the same blast-furnace slag content. Although incorporating dry activator content equivalent to 3 wt.% NaOH accelerated the setting time and enhanced the workability and early compressive strength, it demonstrated the lower compressive strength at later ages of curing. Accordingly, sodium hydroxide content within dry activator played an important role in the performance of the prepared mortar, especially at later ages of hydration. As suggested by the reaction mechanism, dry activator is mainly composed of sodium calcium aluminosilicate species with a high ability to re-interact with water, yielding calcium aluminum silicate hydrate and sodium hydroxide. The liberated sodium hydroxide accelerated the dissolution of unreacted slag particles, resulting in an acceleration in the hydration products formation which coincided with compressive strength improvement. As identified by X-ray diffraction and thermogravemetric analyses, calcium silicate hydrate, calcium aluminum silicate hydrate, and chabazite zeolite are the dominant hydration products with the prepared hybrid cement. It can be said that preparatig dry activator resolved the drawback of the corrosive nature of alkaline solution, which could strongly reflect on the safe use of hybrid cement in different construction projects.

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No competing interests reported.

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An Innovative Method for the Sustainable Utilization of Blast-furnace Slag in the Cleaner Production of One-part Hybrid Cement

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Abstract

Figures

1. Introduction

2. Experimental

2.1. Materials resources

2.2. Preparation of one-part hybrid cement powder

3.3. Preparation of one-part-HC mortar

3.4. Experimental methods

3.5. Instrumental techniques

3. Results And Discussion

3.1. Characterization of DAS

4. Conclusions

References

Additional Declarations

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