The Appearance and Petrology of Meteorites
Kumtag meteorites show various surface characteristics. Some stones are completely covered with black fusion crust and show well developed regmaglypts (Fig. 3a). Part of the meteorites in contact with the desert sand are often covered with rust (Fig. 3b), which was formed during terrestrial weathering. Note that the rusty spot on the ground-touching surface is very often a strong indicator for hot-desert meteorites, especially for relatively iron-rich ordinary chondrites, particularly from the H group. The largest meteorite of the strewn field with a mass of 10.05 kg is shown in Fig. 3c. The individual is only on one side covered with fusion crust and regmaglypts; the broke surface indicates the meteorite fragment was even bigger (Fig. 3c). Highly fractured meteorites were also collected; their cracks were often partially filled with sand (Fig. 3d). In hot desert environments, meteorites often break into dozens of pieces during their landing and/or during terrestrial weathering (Fig. 3e). Two meteorites with a secondary fusion crust were collected. Form the geometry is obvious that these two objects belong to the same fragment of the meteorite shower (Fig. 3f).
The eight studied Kumtag meteorite samples have similar mineral composition, shock characteristics, and weathering grade. The meteorites are mainly composed of olivine, pyroxene, plagioclase, Fe-Ni metal, troilite, and some weathering products (Fig. 4). Texturally, the boundaries of the chondrules are vague but distinct. The plagioclase grain size is mostly between 2 ~ 50 µm. Consequently, Kumtag is a type 5 chondrite (Van Schmus and Wood 1967). The average fayalite (Fa) content of olivines and the average ferrosilite (Fs) content of the low-Ca pyroxenes are 18.50 ± 0.31 mol% and 16.60 ± 0.69 mol% (Table 1), respectively, clearly indicating that Kumtag is a H chondrite (Brearley and Jones 1998; Weisberg et al. 2006). On the polished section and under the electron microscope most of the olivine grains show irregular fractures and wavy edges. None of the studied sections showed shock induced melt veins, which suggests that the meteorites suffered relatively weak shock corresponding to shock stage S1 or S2 (Stoffler et al. 1991). In the studied sections, about 25 vol% of the Fe-Ni metal has been replaced by weathering products, indicating weathering degree W2 (Wlotzka 1993).
Table 1
Electron probe analysis of olivine (Ol) and pyroxene (Pyx) in Kumtag meteorite. The uncertainties are 1SD, Ol represents olivine and Pyx represents pyroxene.
Sample
|
mineral
|
Na2O
|
MgO
|
Al2O3
|
K2O
|
FeO
|
MnO
|
TiO2
|
CaO
|
NiO
|
Cr2O3
|
SiO2
|
Total
|
Fa/Fs
|
Kumtag-2
|
Ol
|
0.01 ± 0.01
|
29.6 ± 0.9
|
0.16 ± 0.02
|
0.03 ± 0.01
|
10.8 ± 0.1
|
1.16 ± 0.07
|
0.41 ± 0.18
|
0.84 ± 0.03
|
0.05 ± 0.07
|
0.19 ± 0.05
|
56.1 ± 1.2
|
99.4 ± 0.4
|
18.6 ± 0.3
|
Pyx
|
0.00 ± 0.01
|
42.0 ± 0.9
|
0.01 ± 0.01
|
0.01 ± 0.01
|
17.2 ± 0.5
|
1.06 ± 0.10
|
0.07 ± 0.09
|
0.03 ± 0.01
|
0.03 ± 0.02
|
0.02 ± 0.02
|
39.1 ± 0.6
|
99.6 ± 0.9
|
16.9 ± 0.3
|
Kumtag-3
|
Ol
|
0.00 ± 0.00
|
29.9 ± 1.9
|
0.12 ± 0.03
|
0.03 ± 0.05
|
10.8 ± 0.2
|
1.15 ± 0.30
|
0.06 ± 0.06
|
0.53 ± 0.29
|
0.03 ± 0.01
|
0.13 ± 0.01
|
55.6 ± 1.6
|
98.5 ± 0.6
|
18.3 ± 0.2
|
Pyx
|
0.01 ± 0.02
|
43.2 ± 0.4
|
0.00 ± 0.00
|
0.04 ± 0.03
|
17.2 ± 0.1
|
1.13 ± 0.04
|
0.06 ± 0.03
|
0.03 ± 0.01
|
0.02 ± 0.02
|
0.00 ± 0.00
|
38.2 ± 0.1
|
100.0 ± 0.3
|
16.4 ± 0.6
|
Kumtag-4
|
Ol
|
0.03 ± 0.01
|
30.3 ± 0.1
|
0.30 ± 0.15
|
0.04 ± 0.05
|
11.3 ± 0.5
|
1.08 ± 0.11
|
0.59 ± 0.18
|
0.78 ± 0.01
|
0.03 ± 0.04
|
0.23 ± 0.14
|
54.4 ± .9
|
99.0 ± 1.1
|
18.5 ± 0.3
|
Pyx
|
0.01 ± 0.01
|
42.6 ± 1.1
|
0.00 ± 0.01
|
0.00 ± 0.00
|
17.2 ± 0.1
|
0.99 ± 0.16
|
0.14 ± 0.07
|
0.02 ± 0.01
|
0.03 ± 0.22
|
0.01 ± 0.01
|
37.6 ± 0.5
|
98.6 ± 0.5
|
16.9 ± 0.7
|
Kumtag-5
|
Ol
|
0.02 ± 0.01
|
30.1 ± 0.6
|
0.21 ± 0.02
|
0.02 ± 0.03
|
11.0 ± 0.3
|
1.15 ± 0.13
|
0.39 ± 0.12
|
0.82 ± 0.01
|
0.04 ± 0.01
|
0.18 ± 0.03
|
55.1 ± 0.5
|
98.9 ± 0.7
|
18.7 ± 0.4
|
Pyx
|
0.10 ± 0.19
|
42.3 ± 1.4
|
0.01 ± 0.01
|
0.02 ± 0.03
|
17.3 ± 0.2
|
1.09 ± 0.11
|
0.05 ± 0.10
|
0.03 ± 0.02
|
0.01 ± 0.01
|
0.01 ± 0.03
|
38.0 ± 0.9
|
98.9 ± 0.4
|
16.8 ± 0.1
|
Kumtag-6
|
Ol
|
0.04 ± 0.01
|
30.9 ± 0.1
|
0.15 ± 0.03
|
0.01 ± 0.01
|
11.4 ± 0.5
|
1.16 ± 0.04
|
0.14 ± 0.09
|
0.68 ± 0.03
|
0.01 ± 0.01
|
0.15 ± 0.01
|
53.9 ± 0.2
|
98.6 ± 0.7
|
18.5 ± 0.4
|
Pyx
|
0.01 ± 0.01
|
42.4 ± 0.3
|
0.01 ± 0.02
|
0.01 ± 0.01
|
17.2 ± 0.4
|
1.01 ± 0.04
|
0.04 ± 0.05
|
0.03 ± 0.02
|
0.03 ± 0.03
|
0.01 ± 0.01
|
38.0 ± 0.40
|
98.7 ± 0.5
|
17.0 ± 0.6
|
Kumtag-7
|
Ol
|
0.01 ± 0.01
|
30.9 ± .01
|
0.26 ± 0.09
|
0.00 ± 0.00
|
10.7 ± 0.1
|
1.11 ± 0.15
|
0.59 ± 0.11
|
0.67 ± 0.13
|
0.02 ± 0.02
|
0.18 ± 0.10
|
55.3 ± 0.1
|
99.8 ± 0.6
|
18.5 ± 0.4
|
Pyx
|
0.03 ± 0.02
|
42.8 ± 0.7
|
0.01 ± 0.02
|
0.00 ± 0.01
|
17.2 ± 0.3
|
0.95 ± 0.11
|
0.03 ± 0.05
|
0.01 ± 0.01
|
0.01 ± 0.02
|
0.01 ± 0.01
|
38.9 ± 0.6
|
100.0 ± 1.0
|
16.1 ± 0.1
|
Kumtag-8
|
Ol
|
0.00 ± 0.00
|
31.3 ± 0.6
|
0.26 ± 0.15
|
0.04 ± 0.06
|
10.9 ± 0.2
|
1.25 ± 0.09
|
0.45 ± 0.13
|
0.69 ± 0.03
|
0.03 ± 0.01
|
0.41 ± 0.35
|
53.2 ± 1.1
|
98.5 ± 0.7
|
18.5 ± 0.3
|
Pyx
|
0.02 ± 0.01
|
42.8 ± 0.8
|
0.02 ± 0.02
|
0.01 ± 0.01
|
17.4 ± 0.2
|
0.93 ± 0.15
|
0.03 ± 0.04
|
0.05 ± 0.03
|
0.06 ± 0.07
|
0.02 ± 0.02
|
38.4 ± 0.4
|
99.7 ± 0.9
|
16.1 ± 0.5
|
Kumtag-9
|
Ol
|
0.02 ± 0.01
|
30.7 ± 0.8
|
0.11 ± 0.01
|
0.01 ± 0.01
|
11.2 ± 1.0
|
1.10 ± 0.09
|
0.11 ± 0.19
|
0.64 ± 0.19
|
0.06 ± 0.06
|
0.12 ± 0.01
|
55.8 ± 0.7
|
99.8 ± 0.8
|
18.5 ± 0.3
|
Pyx
|
0.01 ± 0.02
|
43.0 ± 0.6
|
0.01 ± 0.01
|
0.00 ± 0.01
|
17.4 ± 0.4
|
1.11 ± 0.10
|
0.12 ± 0.10
|
0.03 ± 0.01
|
0.03 ± 0.02
|
0.02 ± 0.02
|
38.5 ± 0.7
|
100.2 ± 0.6
|
16.8 ± 1.5
|
Cosmic-Ray Exposure Ages, Preatmospheric size, and Gas Retention Ages
The concentrations and isotopic ratios of the light noble gases He, Ne, and Ar were measured in one Kumtag meteorite. The results, corrected for blank contributions and instrumental mass fractionation, are shown in Table 2. For the component deconvolution, we assume that the measured Ne and Ar concentrations are mixtures between cosmogenic (“c”) and trapped (“tr”) components, the latter being atmospheric contamination. Note that atmospheric contamination is very common for hot desert, weathered meteorites (e.g., Huber et al. xxx). For calculating 21Nec and 38Arc via the component deconvolution we use the following endmembers: (20Ne/22Ne)c = 0.84, (36Ar/38Ar)c = 0.65, (20Ne/22Ne)air = 9.80, (21Ne/22Ne)air =0.029, and (36Ar/38Ar)air = 5.35 (Eberhardt et al. 1965; Lee et al. 2006). Note that the cosmogenic endmember composition (20Ne/22Ne)c = 0.84 corresponds to the measured ratio, which clearly indicates that the amount of atmospheric contamination for Ne isotopes is only very minor. We further assume that the measured 3He concentration is entirely cosmogenic. The thus calculated cosmogenic 21Nec and 38Arc concentrations are given in Table 3. The production rates were calculated using the model by Eugster (1988) and the cosmic-ray exposure (CRE) ages are given in Table 4. The CRE ages T3, T21, and T38, based on 3Hec, 21Nec, and 38Arc concentrations, respectively, of the Kumtag meteorite are 6.3 ± 1.9 Ma, 6.2 ± 1.9 Ma, and 7.7 ± 2.4 Ma, respectively. The grand average CRE age is 6.7 ± 0.8 Ma, which represents the CRE age of the Kumtag strewn field meteorite. The weathering degree of the Kumtag strewn field is W2, indicating a relatively short terrestrial age. From this finding it is therefore safe to assume that the CRE age of Kumtag is very close to the ejection age, i.e., 6.7 ± 0.8 Ma. The thus determined CRE (or ejection) age is consistent with typical CRE ages for other H chondrites, which have a peak centered at about 7 Ma in the CRE age histogram (Herzog 2007). The preatmospheric size and the mass of a meteorite can be estimated using the cosmogenic (22Ne/21Ne)c ratio, which is a known indicator for shielding (Bhandari et al. 1980; Leya and Masarik 2009). From the empirical equation given by Bhandari et al. (1980) and the (22Ne/21Ne)c ratio of 1.083 ± 0.017, we calculate a preatmospheric mass of 115.8 ± 32.6 kg, which is in contradiction to the total recovered mass of all Kumtag meteorites of > 180 kg. Possibilities to account for such a difference are i) Kumtag was not a spherical object and the effective radius was much smaller than the estimated radius, ii) the correlation between (22Ne/21Ne)c and spherical size deduced from Bhandari et al. (1980) is not applicable for the Kumtag meteorite because this special sample might come from an outer layer of the meteorite. Note also that the correlation given by Bhandari et al. (1980) only gives a lower limit for the preatmospheric mass (Zeng et al. 2018). From the total recovered mass of ~ 180 kg, an average bulk density of 3.567 g/cm3, and assuming an ablation loss of ~ 87% (Bhandari et al. 1980) we calculate a pre-atmospheric radius of ~ 45 cm (Li et al. 2019).
Table 2
He, Ne, and Ar isotopic concentrations of the Kumtag meteorite (10− 8 cm3 STP g− 1).
Meteorite
|
Type
|
Mass (mg)
|
3He
|
4He
|
22Ne
|
36Ar
|
40Ar
|
20Ne/22Ne
|
21Ne/22Ne
|
36Ar/38Ar
|
Kumtag
|
H5
|
71.33
|
10.1 ± 0.6
|
877 ± 48
|
2.61 ± 0.19
|
0.989 ± 0.034
|
4367 ± 76
|
0.846 ± 0.013
|
0.919 ± 0.014
|
1.88 ± 0.05
|
Table 3
Cosmogenic and radiogenic noble gases of the Kumtag meteorite (10− 8 cm3 STP g− 1). “c” and “r” represent cosmogenic and radiogenic nuclides components.
Meteorite
|
Type
|
Mass (mg)
|
3Hec
|
21Nec
|
38Arc
|
(22Ne/21Ne)c
|
4Her
|
40Arr
|
Kumtag
|
H5
|
71.33
|
10.1 ± 0.6
|
2.40 ± 0.18
|
0.385 ± 0.027
|
1.083 ± 0.017
|
827 ± 48
|
4147 ± 72
|
Table 4
Cosmic-ray exposure ages and retention ages of the Kumtag meteorite (in Ma). The gas retention ages were calculated using average K, U, Th, and Sm concentrations for H ordinary chondrites (Lodders and Fegley 1998).
Meteorite
|
Type
|
Mass (mg)
|
T3
|
T21
|
T38
|
Adopted age
|
T4
|
T40
|
T3/T21
|
T4/T40
|
Kumtag
|
H5
|
71.33
|
6.3 ± 1.9
|
6.2 ± 1.9
|
7.7 ± 2.4
|
6.7 ± 0.8
|
2508 ± 170
|
3908 ± 227
|
1.02 ± 0.44
|
0.64 ± 0.06
|
For calculating the 4He gas retention age of the Kumtag meteorite, we use the average U, Th, and K concentrations for H-group ordinary chondrites given by Lodders and Fegley (1998). The concentration of radiogenic 4He (4Her) and 40Ar (40Arr) have been determined by subtracting cosmogenic 4He and trapped 40Ar contributions, respectively (Table 3). The thus determined gas retention ages are T4 = 2508 Ma and T40 = 3908 Ma (Table 4), i.e., T4 is significantly lower than T40. Consequently, the Kumtag meteorite plots to the left of the solid line with slope 1 (Fig. 5). In this diagram, samples with identical CRE ages based on 3He and 21Ne plot close to 1 on the y-axis and samples with identical T4 and T40 plot close to 1 on the x-axis. Samples that simultaneously lost 3He and 4He move along the line with slope 1. For the studied meteorite we have T3/T21 = 1.02 ± 0.44 and T4/T40 = 0.64 ± 0.06. The T3/T21 ratio of 1.02 ± 0.44 suggests no or only minor losses of cosmogenic 3He and/or 3He. This finding is further confirmed when studying the data in a diagram (3He/21Ne)c vs. (22Ne/21Ne)c, i.e., in the Bern-plot (Nishiizumi et al. 1980) (Fig. 6). Also, this data indicates no or only little losses of cosmogenic 3He and/or 3He.
In contrast, the ratio T4/T40 of 0.64 ± 0.06 is significantly lower than 1, indicating loss of radiogenic 4He. Since the 4He loss is not accompanied by 3He loss, it likely occurred before ejection of the Kumtag meteorite from the H chondrite parent body. The exact reason for the loss of radiogenic He is unclear but it might be connected to the severe heating of the H-chondrite parent body, remember that Kumtag is a type 5 H-chondrite. It is unlikely that the 4He loss was caused by a shock event, because the studied Kumtag individual has a shock stage of only S2. However, it cannot be excluded that the 4He and/or 40Ar gas retention age are too high or too low due to wrong assumptions about U, Th, and K concentrations.