5. 1 Waveform analysis
The voltage and current waveforms of the four mediums during machining were acquired using a DEWEsoft SIRIUS multi-channel data acquisition system. Fig. 7 extracts the discharge waveforms during the 6-ms time interval. Deionization is easily accomplished after Pulse switch out, which generates some spark waveforms during machining[23], and at the same time, the DI water has weak electrical conductivity, leakage current is generated during the spark breakdown delay phase, which can lead to microelectrolysis[24], and machining in DI water can be classified as SEAM, EDM-ECM combined machining. When the medium is electrolyte only, the waveforms are all electrolytic waveforms and the maximum electrolytic current is 32A. Therefore, no sparks and arcs are observed to occur during the machining process. When the medium is DI water and air, due to the strong dielectric ability of gas, it is more likely to lead to self-sustaining discharge to form arcs, but some unsteady arcs are generated due to the rotation of the electrode and the violent gas disturbance in the narrow gap. When the medium is electrolyte and air, the waveforms are distributed at intervals of arcs and electrolysis, which shows that SEAM and ECM are alternated during the machining process, but the electrolysis current and arc current are reduced compared with both pure arc machining and pure electrolysis machining, the energy acting on the workpiece surface is reduced, which is beneficial to reduce the thickness of the recast layer on the workpiece surface.
5. 2 Surface morphology and elemental analysis
Fig. 8 shows the microscopic surface morphology of the workpiece under different medium conditions. The surface of the workpiece machined with DI water shows a large number of molten droplets, particles, holes, and a thick build-up of recast layer, which is a result of the uneven re-solidification of the molten metal on the surface of the workpiece due to the poor flushing conditions. The number of molten droplets and particles on the surface of the workpiece machined with the combination of DI water and air is very small. However, due to the high pulse energy, cracks are found all along the vertical direction of the recast layer. Since the titanium alloy finish ion exchange in the electrolyte and form light flocculent material, which easily flow out of the gap, the surface products accumulation phenomenon of using electrolyte machining and combined electrolyte and air machining is greatly improved, the surface defects such as molten droplets, particles and holes basically do not exist on the surface. Because ECM is performed, no defects such as obvious recast layers and microcracks are observed on the workpiece surface. However, there are still some flocculent electrolytic products deposit on the surface of the workpiece, which indicates that there is still room for improvement in the effect of the flushing.
According to the energy dispersive spectroscopy (EDS)analysis of the surface. The carbon content of the solidification processed using electrolyte and air increased significantly, due to the electrolysis of CO2 in air at high temperature to produce CO, CO continues to decompose into free C adsorb on the surface of the titanium alloy and diffuses to the base material to generate TiC[25], which achieve the carburization effect. The oxygen content under this machining condition is also slightly elevated compared to DI water and air machining, because oxygen is also an intermediate product of the electrolysis reaction. In addition, chlorine is detected on the surfaces machined with electrolyte and air, indicating the migration of solution elements to the workpiece in addition to ambient gases.
X-ray diffraction analysis of the four workpiece surface micro-areas marked by the red area in Fig. 8 and the workpiece substrate is carried out as shown in Fig. 9. Titanium alloy forms dense oxide films TiO2 and TiO on the surface at room temperature, and a small amount of Ti elemental exists on the surface. After machining the spectrum is shifted, indicating the generation of residual stresses, the DI water machining surface defects are serious and have obvious residual stresses. When air is added to the medium, Ti2O3 is produced due to peroxidation, in addition the intermediate product of the titanium alloy in the halide electrolyte is the corresponding halide TiCl4[26], but it is highly hydrolyzed, so only chlorine is detected on the surface and not TiCl4. The surface machined with electrolyte and air underwent both SEAM and ECM, which produces more intermediate products compared to other machining conditions. Table 4 shows the chemical equations for the generation of each phase.
5. 3 Cross-sectional morphology and thickness of recast layer (sediment layer)
Fig. 10 shows the microscopic morphology of the workpiece cross-section under different medium conditions, can be seen that the workpiece cross-section machined with DI water alone has a thicker recast layer, and the migration of carbon and oxygen extends into the recast layer to produce larger residual stresses to increase cracks[27]. Due to poor flushing conditions, heat cannot be dissipated in time, excessive heat extension to the base material leads to a similarly large thickness of the heat-affected zone. Although the pulse energy of the combined DI water and air machining is higher, the recast layer thickness is weakened by the addition of high pressure air which improves the flushing conditions and makes it easier for the products to pass out the gap. Obviously, the cooling performance is significantly improved with the addition of air, the thickness of the heat-affected zone is significantly reduced. Comparing the cross-section machined with electrolyte and the combination of electrolyte and air, the difference is not significant. The thickness of the sediment layer is low because of the small mass of the electrolytic products and the easy to pass of the gap, and the low thermal conductivity of the titanium alloy, the heat generated by ECM is not enough to conduct to the base material, so there is basically no heat-affected zone. Although more heat is generated by using a combination of electrolyte and air, the cooling properties of the mixed medium compensate for this machining defect, and there is no significant heat-affected zone in the workpiece cross-section.
Intercepted 10 locations of the workpiece recast layer(deposited layer)cross-section according to Fig. 10, measured the thickness of the recast layer there, and plot Fig. 11. The average recast layer thickness for machining with DI water alone is 54.9սm, while the recast layer thickness for machining with a combination of air and electrolyte is reduced by 72.7% relative to DI water, and increased by only 5.97% relative to machining with electrolyte alone, significantly improving the machining quality of SEAM.
Fig. 12 selected cross-section recast layer(sediment layer), heat-affected zone and base material for microhardness analysis, as shown in the figure, because TiO2 and TiC can form a continuous solid solution, the hardness of recast layer(sediment layer)is much higher than that of heat-affected zone and base material, the hardness of heat-affected zone and base material are basically the same, which means that TiC has not penetrated recast layer(sediment layer), and the heat-affected zone material has not undergone obvious phase change.
5. 4 Cross-sectional dimensional accuracy
Due to the symmetry of dimensional errors caused by electrode rotation, half of the shape of the same position in the middle of the intercepted milling slot is made symmetrical, as shown in Fig. 13. The specified dimension of the milled slot is 2 mm, and the machining with DI water is too low energy to reach the specified depth of cut, while the machining with a combination of DI water and air causes the phenomenon of overcutting due to the concentration of energy. In order to evaluate in detail the influence of the medium characteristics on the dimensional accuracy, the milling depth error is evaluated according to the absolute value of the difference between the actual milling depth H and the standard milling depth, and the shape error of the milling slot is evaluated according to the milling slot tilt angle θ, as shown in Fig. 14.
Fig. 15 shows both the milling groove depth error and tilt angle θ under different medium conditions. Combining with Fig. 7, it can be seen that pulse energy and milling groove depth are positively correlated, therefore, the milling groove depth is increased for both air addition machining, and ECM will also produce overcutting because of the existence of exceeding corrosion. Combining with Fig 5, it can be seen that the gas addition makes the liquid medium diffuse toward the electrode edge, so that the electrolyte can directly contact the side of the milling groove and ECM occurs at the corner of the milling groove. Therefore, the combined machining using air and electrolysis has a significant improvement in cross-sectional shape accuracy compared with other forms of machining. SEAM-ECM reduces θ by 55.56% compared to pure arc machining and by 68% compared to pure electrolytic machining.
In order to comprehensively evaluate the dimensional accuracy of the milled slot, the milling depth error and tilt angle are Min-Max normalized according to equation(4):
where Min, Max are the minimum and maximum values of the samples respectively.
Since both the milling groove depth error and the tilt angle are consistent with the lookout small characteristic, the dimensional accuracy is evaluated by taking the average of the two. Table 5 shows the dimensionless numbers of the combined calculation, and it can be seen that the dimensional accuracy of the milled groove machined with the combination of electrolyte and air is optimal.
5. 5 Surface roughness
The center area of the milling groove is selected for observation and measurement, and the 3D shape of the surface is shown in Fig. 16. When the medium is DI water, the flow velocity of the gap flow field is low, and the particles easy to accumulate on the workpiece surface, so many bumps can be seen on the workpiece surface, and therefore the surface roughness is as high as 63.49սm. The surface roughness of ECM alone decreased by 20.28% compared to SEAM using DI water. The analysis concluded that the surface roughness is lower because the ECM machining products are light flocculent, while ECM is smoother compared to SEAM and the products are easier to clear the gap, but the surface finish after machining is still unsatisfactory due to the poor flushing conditions and the presence of stray corrosion in ECM. The surface roughness of the combined DI water and air machining is the highest. Although the addition of gas reduces the accumulation of particles, the higher pulse energy acts on the surface of the workpiece, producing large and deep craters. When combined electrolyte and air machining is used, the surface finish is significantly improved. On the one hand, there are no particles buildup, and on the other hand, no deep craters are produced due to the dispersion of SEAM energy by ECM, and ECM polishing is also performed, which increase the surface roughness by 41.61% relative to pure arc machining and 24.14% relative to pure electrolytic machining.
5. 6 Comprehensive surface integrity evaluation
Fig. 17 describes the comprehensive surface integrity evaluation of the recast layer thickness, surface roughness, and dimensional accuracy of the workpiece cross-section after machining in different mediums. Three indicators satisfy the lookout small characteristic, from the figure, it can be seen that the machining using the combination of DI water and air is the least satisfactory, and the high pulse energy leads to deep pits and thick recast layer, which can indicate that the pulse energy has a certain negative correlation with the surface integrity. And electrolytic machining may lead to a lower surface finish due to stray corrosion problems. In terms of the overall capability, machining with a combination of electrolyte and air has a more balanced performance compared to other mediums.